2019
DOI: 10.26434/chemrxiv.11342096
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Ru-Catalyzed Carbonylative Murai Reaction: Directed C3-Acylation of Biomass-Derived 2-Formyl Heteroaromatics

Abstract: <p>We describe here the carbonylative Murai reaction applied to 2-formylfurans, 2-formylpyrrols and 2-formylthiophenes. Thanks to the installation of removable imine directing groups, this acylation reaction takes place regioselectively at C3 position of the heterocyclopentadienes. It can be achieved by treating the two reaction partners with a catalytic amount of Ru<sub>3</sub>(CO)<sub>12</sub>, in toluene at 120-150 °C, after CO bubbling, at atmospheric pressure. DFT computation… Show more

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