Ru nanoparticle decorated Ni(OH)<sub>2</sub> nanosheets for highly efficient electrochemical synthesis of 2,5-furandicarboxylic acid: experimental and theoretical studies

Cheng, Zhong; Fu, Dingbang; Zhou, Wenjing; Deng, Wenfang; Tan, Yueming; Ma, Ming

doi:10.1039/d3ta04963a

J. Mater. Chem. A

2023

DOI: 10.1039/d3ta04963a

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Ru nanoparticle decorated Ni(OH)₂ nanosheets for highly efficient electrochemical synthesis of 2,5-furandicarboxylic acid: experimental and theoretical studies

Zhong Cheng,

Dingbang Fu,

Wenjing Zhou

et al.

Abstract: Ru nanoparticle decorated Ni(OH)2 is developed as a high-performance catalyst for the electrochemical synthesis of 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid.

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Cited by 7 publications

References 47 publications

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High‐efficient electrocatalytic CO₂ reduction to HCOOH coupling with 5‐hydroxymethylfurfural oxidation using flow cell

Ren,

Li,

Ning

et al. 2024

AIChE Journal

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Among various products from electrocatalytic CO2 reduction (CO2ER), HCOOH is highly profitable one. However, the slow kinetics of anodic oxygen evolution reaction lowers overall energy efficiency, which can be replaced by an electro‐oxidation reaction with low thermodynamic potential and fast kinetics. Herein, we report an electrolysis system coupling CO2ER with 5‐hydroxymethylfurfural oxidation reaction (HMFOR). A BiOCl–CuO catalyst was designed to sustain CO2ER to HCOOH at partial current density of 500 mA/cm2 with FEHCOOH above 90% and 700 mA/cm2 with FEHCOOH above 80%. In situ and ex situ x‐ray absorption fine structure was used to capture the structure transform of BiOCl–CuO into metallic Bi and Cu during CO2ER process, and the presence of CuO will promote this transformation which are supported by DFT calculations. Coupling HMFOR with CO2ER, we realize both FEHCOOH and FEFDCA above 95% simultaneously, providing new prospects vista for the electrosynthesis of value‐added products from paired system.

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High‐efficient electrocatalytic CO₂ reduction to HCOOH coupling with 5‐hydroxymethylfurfural oxidation using flow cell

Ren,

Li,

Ning

et al. 2024

AIChE Journal

View full text Add to dashboard Cite

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Nickel Hydroxide‐Based Electrocatalysts for Promising Electrochemical Oxidation Reactions: Beyond Water Oxidation

Sun,

Song

2024

Small

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Transition metal hydroxides have attracted significant research interest for their energy storage and conversion technique applications. In particular, nickel hydroxide (Ni(OH)2), with increasing significance, is extensively used in material science and engineering. The past decades have witnessed the flourishing of Ni(OH)2‐based materials as efficient electrocatalysts for water oxidation, which is a critical catalytic reaction for sustainable technologies, such as water electrolysis, fuel cells, CO2 reduction, and metal–air batteries. Coupling the electrochemical oxidation of small molecules to replace water oxidation at the anode is confirmed as an effective and promising strategy for realizing the energy‐saving production. The physicochemical properties of Ni(OH)2 related to conventional water oxidation are first presented in this review. Then, recent progress based on Ni(OH)2 materials for these promising electrochemical reactions is symmetrically categorized and reviewed. Significant emphasis is placed on establishing the structure–activity relationship and disclosing the reaction mechanism. Emerging material design strategies for novel electrocatalysts are also highlighted. Finally, the existing challenges and future research directions are presented.

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Stepwise chemical-electrochemical cycles for decoupling modular biomass oxidation and hydrogen evolution

Lin,

Chen,

et al. 2024

Chemical Engineering Journal

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Ru nanoparticle decorated Ni(OH)₂ nanosheets for highly efficient electrochemical synthesis of 2,5-furandicarboxylic acid: experimental and theoretical studies

Abstract: Ru nanoparticle decorated Ni(OH)2 is developed as a high-performance catalyst for the electrochemical synthesis of 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid.

Cited by 7 publications

References 47 publications

High‐efficient electrocatalytic CO₂ reduction to HCOOH coupling with 5‐hydroxymethylfurfural oxidation using flow cell

High‐efficient electrocatalytic CO₂ reduction to HCOOH coupling with 5‐hydroxymethylfurfural oxidation using flow cell

Nickel Hydroxide‐Based Electrocatalysts for Promising Electrochemical Oxidation Reactions: Beyond Water Oxidation

Stepwise chemical-electrochemical cycles for decoupling modular biomass oxidation and hydrogen evolution

Contact Info

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Ru nanoparticle decorated Ni(OH)2 nanosheets for highly efficient electrochemical synthesis of 2,5-furandicarboxylic acid: experimental and theoretical studies

Abstract: Ru nanoparticle decorated Ni(OH)2 is developed as a high-performance catalyst for the electrochemical synthesis of 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid.

Cited by 7 publications

References 47 publications

High‐efficient electrocatalytic CO2 reduction to HCOOH coupling with 5‐hydroxymethylfurfural oxidation using flow cell

High‐efficient electrocatalytic CO2 reduction to HCOOH coupling with 5‐hydroxymethylfurfural oxidation using flow cell

Nickel Hydroxide‐Based Electrocatalysts for Promising Electrochemical Oxidation Reactions: Beyond Water Oxidation

Stepwise chemical-electrochemical cycles for decoupling modular biomass oxidation and hydrogen evolution

Contact Info

Product

Resources

About

Ru nanoparticle decorated Ni(OH)₂ nanosheets for highly efficient electrochemical synthesis of 2,5-furandicarboxylic acid: experimental and theoretical studies

High‐efficient electrocatalytic CO₂ reduction to HCOOH coupling with 5‐hydroxymethylfurfural oxidation using flow cell

High‐efficient electrocatalytic CO₂ reduction to HCOOH coupling with 5‐hydroxymethylfurfural oxidation using flow cell