2004
DOI: 10.1002/pen.20129
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Rubber plasticizers from degraded/devulcanized scrap rubber: A method of recycling waste rubber

Abstract: Seeking a solution to the problem of disposing scrap tires, we attempted to depolymerize or degrade vulcanized rubber scrap such that the resulting pseudo-liquid material could be used as an extender/plasticizer in virgin rubber compounds. As degraded natural rubber (DNR) and degraded styrene-butadiene rubber (DSBR) are polymeric in nature (confirmed from gel-permeation chromatography (GPC) and differential scanning calorimetry (DSC) results), they can be unique substitutes for typical rubber plasticizers (oil… Show more

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Cited by 17 publications
(9 citation statements)
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“…Disposal of used and discarded tyres has posed a significant environmental threat world wide every year due to the fire hazards and also habitat for insects/rodents 1, 2. Over recent years, the recycling industry has invested in modern technologies to produce crumb from tyre rubber while removing steel, fibers, and other contaminants 3–7. One of the means for utilizing crumb rubber is in the bitumen as rheology modifier for making rubberized bitumen8 because it contains a variety of rubber polymers, predominantly natural rubber and styrene‐butadiene rubber.…”
Section: Introductionmentioning
confidence: 99%
“…Disposal of used and discarded tyres has posed a significant environmental threat world wide every year due to the fire hazards and also habitat for insects/rodents 1, 2. Over recent years, the recycling industry has invested in modern technologies to produce crumb from tyre rubber while removing steel, fibers, and other contaminants 3–7. One of the means for utilizing crumb rubber is in the bitumen as rheology modifier for making rubberized bitumen8 because it contains a variety of rubber polymers, predominantly natural rubber and styrene‐butadiene rubber.…”
Section: Introductionmentioning
confidence: 99%
“…Depolymerizing or degrading vulcanized rubber scrap is a way to produce pseudoliquid material which can be used as an extended plasticizer in virgin rubber compounds. This recycling strategy was used for scrap tires [6] and a similar approach was also extended to the case of PVC/PU blends [7]. Grigoryeva et al performed the partial thermochemical destruction of soundproof material waste and obtained a thermoplastic mixture of PVC and regenerated linear PU.…”
Section: Introductionmentioning
confidence: 99%
“…The recycling include physical 2,3 biological 4 and chemical processes 5,6 that permit obtaining new materials, such as small molecular weight molecules and plasticizers.…”
Section: Introductionmentioning
confidence: 99%