Synthetic alexandrite is being fluxgrown in Rz~ssia in a molybdenum-, bismuth-, and germanium-bearing solvent by means o{ the reverse-temperature gradient method. Characteristic properties include habit, twinning, growth patterns, residzial flux inclusions, trace-element contents, chemical zoning, color zoning, and spectroscopic feat~zres in the visible and infrared ranges. The relationship between production technique and characteristic properties is discussed, and diagnostic properties that can be used to distinguish these synthetics from natural alexandrite are disclosed.h e alexandrites are even rarer than fine rubies! sapphires, and emeralds. The major factors determining (F price are size! clarity! brilliancy! color in daylightl color change in artificial light! and country of origin. The finest alexandrites are characterized by a lively and intense green color in daylight with a prominent color change to purplish red or redhsh purple in incandescent l&t. The most prestigious source of natural alexandrites is Russia! specifically the Ural mountains, where they were first discovered. Fine alexandrites occasionally appear at international auctions. For example! a 31 ct alexandrite sold for almost US$185,000 at Christie's May 1992 auction in Geneva. Dealers in IdarOberstein report the sale of fine! large (over 5 ct) alexandrites for $101000-$201000 per carat, and even higher for exceptional stones (R. Guerlitz and A. Wild! pers. comm.r 1996).During the past 10 years! new deposits of natural alexandrite have been found in Minas Gerais! Brazil (Banlz et al.! 1987; Proctorl 1988; Cassedanne and Roditi, 1993; Karfunlzel and Wegner! 1993); in Orissa and Madhya Pradesh! India [Patnailz and Nayalzl 1993;Newlay and Pashine! 1993); and! most recently! near Songea in southern Tanzania (see ''News on the Songea Deposit . . . Kammerling et al.! 1995).In addition! gem alexandrites are still being recovered from the historic emerald deposits of the Ural Mountains (Eliezri and Kremlzowl 1994; Laslzovenlzov and Zhernalzovl 1995).As greater quantities of gem alexandrite enter the marlzet! significant amounts of faceted alexandrites are being submitted to gemological laboratories for testing. occasion ally^ distinguishing natural from synthetic has been difficult! notably for flux-grown syntheticsl but especially when a specimen lacks diagnostic mineral incl~~sions (see Banlz et al.! 1988; H e m and Banlzl 1992; Kammerhg, 1995). These difficulties are caused by the similarity of growth structures and healing "feathers" in natural alexandrites from different localities to residual flux feathers in fluxgrown synthetic alexandrites. In addition! hematite platelets in natural alexandrites sometimes resemble platinum inclusions in their flux-grown synthetic counterparts.
Synthetic Alexandite GEMS & GEMOLOGY Fall 1996The Russian-produced synthetic alexandrites (figure 1) can imitate the highest-quality nat~lral alexandrites-such as those from the Ural mountains. Yet some natural alexandrites have sold for up to 300 times as much ...