Surface
instabilities are a versatile method for generating three-dimensional
(3D) surface microstructure. When an elastomeric film weakly bonded
to a substrate is swollen with solvent, buckle delamination and subsequent
sliding of the film on the substrate lead to the formation of tall,
self-contacting, and permanent folds. This paper explores the mechanics
of fold development when such folding is induced by placing a drop
on the surface of the film. We show that capillary effects can induce
a strong coupling between folding and drop spreading: as folds develop,
they wick the solvent toward the periphery of the drop, further propagating
radially aligned folds. Accordingly, a solvent drop spreads far more
on films that are weakly adhered to the substrate. As drop size reduces
and folding becomes increasingly confined, debonding propagates along
the perimeter of the wetted region, thus leading to corral-shaped
fold patterns. On the other hand, as drop size increases and confinement
effects weaken, isotropically oriented folds appear at a spacing that
reduces as swelling increases. The spacing between the folds and the
size of the corrals are both determined by the extent to which a single
fold relieves compressive stress in its vicinity by sliding. We develop
a model for folding which explicitly accounts for the fact that folds
must initiate with near-zero volume under the buckle. The model shows
that folds can appear even at very low swelling if there are large
pre-existing debonded regions at the film–substrate interface.