{RuII(NO+)}3+-core complexes with 4-methyl-pyrimidine and ethyl-isonicotinate: Synthesis, X-ray structure, spectroscopy, and computational and NO-release studies upon UVA irradiation

On the Electronic Structure ofmer,trans‐[RuCl3(1H‐indazole)2(NO)], a Hypothetical Metabolite of the Antitumor Drug Candidate KP1019: An Experimental and DFT Study

“…However, this notation leaves the actual physical and formal oxidation state [23] of the metal center and nitrosyl ligand unclear, and therefore it remains a subject of notable interest. [24][25][26][27][28][29][30][31][32][33][34][35][36][37] This study is an attempt to describe such a {Ru(NO)} 6 -containing system in more detail.…”

Cytotoxicity and Crystal Structures of Nitrosoruthenium Complexes mer‐[Ru(NO)Py2Cl3] and mer‐[Ru(NO)(γ‐Pic)2Cl3]

“…Bond angles at ruthenium are very close to 90°, while Ru‐N−O angle is nearly linear in both structures I and II , that is commonly for nitrosyl‐group with formula {RuNO} 3+ . The general distances and angles in the both structures (Table ) are also close to characteristic values for these type of compounds ,. Some differences in Ru−Cl, Ru‐N NO and N−O bonds are likely due to the above mentioned disorder of chloride and nitrosyl ligands.…”

“…The structure of II contains two independent molecules mer ‐[Ru(NO)(γ‐Pic) 2 Cl 3 ]; the first one shows the same disordering, while the second one reveals two positions with fully occupied Cl – and with Cl – /NO ligands of 0.5/0.5 occupancies. This type of disorder is well‐known for the compounds with Ru(NO)Cl 3 plane ,…”

“…The water insoluble complex mer‐[Ru(NO)Py 2 Cl 3 ] have been obtained a few times through the different synthetic procedures as admixture,, but the crystal structure of this complex hasn't been studied until now. There are complexes with other amine ligands known mer‐[Ru(NO)(L) 2 Cl 3 ], (where L – ethylisonicotinate or 4‐methylpyrimidine,, and 4‐cyanopyridine or 4‐aminopyridine) have been synthesized with yields 60–70% and structurally characterized by single‐crystal XRD, where Ru(NO)Cl 3 ⋅ n H 2 O was used as a precursor. The related picoline complexes were not presented in the literature until today.…”

Metalloligand-based coordination polymer embedding the nitrosyl ruthenium complex for photoactive materials with bound nitric oxide

“…Previously, the [RuNO(inicEt) 2 Cl 3 ] complex was synthesized and characterized structurally 25 and its photochemistry was studied in solution. 26 In the present paper, this complex was synthesized with improved yield and in a simplified process. The reaction of K 2 [RuNOCl 5 ] 27 with ethyl isonicotinate was carried out under an ambient atmosphere in DMF.…”