As part of the Carbon Capture and Storage (CCS) process, pipeline transportation is the safest and most economic option for delivering captured CO 2 to a storage site. However, in the event of pipeline rupture an enormous mass of CO 2 may be released very rapidly, presenting several risks to the pipeline and surrounding population including the significantly increased risk of brittle fracture in the pipe wall. The study of pressure variation and phase change in CO 2 during pipeline blowdown can contribute to the understanding of fracture initiation and propagation, as well as downstream CO 2 diffusion behavior. As part of the CO 2 QUEST project, a reusable, industrial scale pipeline experimental apparatus with a total length of 258 m and the inner diameter of 233 mm was fabricated to study pure CO 2 pipeline blowdown. A dual-disc blasting device was used to remotely control the opening of the pipeline. The instantaneous pressure response following release was measured with high frequency pressure transducers. Variation in fluid temperature at the top and bottom of pipeline was also recorded. Six groups of pure CO 2 pipeline release experiments were conducted with initially gaseous and dense phase inventories with three orifice diameters (15 mm, 50 mm and Full Bore Rupture). The pressure undershoots, rebounds and quasi static pressures were observed during the release as result of the propagation of a series of expansion waves. The process of pressure drop and rebound was accompanied by the occurrence of gas-liquid two-phase flow. The complicated phase transitions were obtained during depressurization of gaseous and dense CO 2 releases.