Ruthenium‐Photocatalyzed Synthesis of Borasiloxanes in a One‐Pot Manner from Readily Available Silanes and Pinacolborane

Fan, Baomin; Wu, Wei; Chen, Jingchao; Qiao, Lulin; Lv, Haiping; Zhang, Fuqin; Zhu, Yuanbin; Wu, Shiyuan

doi:10.1002/ajoc.202100544

Asian J Org Chem

2021

DOI: 10.1002/ajoc.202100544

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Ruthenium‐Photocatalyzed Synthesis of Borasiloxanes in a One‐Pot Manner from Readily Available Silanes and Pinacolborane

Baomin Fan

Wei Wu

Jingchao Chen

et al.

Abstract: A three-component reaction of silanes, water and pinacolborane catalyzed by Ru(bpy) 3 Cl 2 has been developed under 20W blue LED irradiation in one-pot manner. The reaction has offered a convenient and atom economical approach to access the useful borasiloxanes by releasing hydrogen gas as the sole by-product.

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Photocatalytic Multi-Component Reactions: An Emerging Avenue

Ariya,

Neetha,

Anilkumar

2023

CCAT

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In recent years, photocatalytic multi-component reactions have emerged as a cutting-edge innovation in the field of organic synthesis. These reactions allow the simultaneous transformation of multiple reactants, which not only saves time and resources but also provides access to a diverse range of complex molecules. The use of photocatalysts in these reactions provides several advantages, including mild reaction conditions, high selectivity, and high functional group tolerance. Moreover, the integration of renewable energy sources such as visible light as a driving force for these reactions further adds to their sustainability. This innovation has opened up new avenues for the synthesis of complex molecules and holds great promise for the development of sustainable and efficient chemical processes. This review gives a broad understanding of photocatalyzed multi-component reaction protocols developed with wide applications in synthetic organic chemistry. These green, efficient, and straightforward reactions utilize recyclable photocatalyst, solvent-free or catalyst-free conditions for the synthesis of compounds with biological significance in a cost-effective fashion. They are easily purified due to the minimum or no by-product formation. The review is divided into sections based on the type of photocatalysts involved and covers literature up to 2022.

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Photocatalytic Multi-Component Reactions: An Emerging Avenue

Ariya,

Neetha,

Anilkumar

2023

CCAT

View full text Add to dashboard Cite

show abstract

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Ruthenium‐Photocatalyzed Synthesis of Borasiloxanes in a One‐Pot Manner from Readily Available Silanes and Pinacolborane

Cited by 1 publication

References 36 publications

Photocatalytic Multi-Component Reactions: An Emerging Avenue

Photocatalytic Multi-Component Reactions: An Emerging Avenue

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