Ruthenium Phthalocyanine: Structure, Magnetism, Electrical Conductivity Properties, and Role in Dioxygen Activation and Oxygen Atom Transfer to 1-Octene

Capobianchi, A.; Paoletti, A.; Pennessi, G.; Rossi, Gentilina; Caminiti, Ruggero; Ercolani, Claudio

doi:10.1021/ic00099a013

Cited by 84 publications

(71 citation statements)

References 3 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Probably the bathochromic shift of the Q band is due to the coordination of ruthenium with atmospheric oxygen. The phenomena described here are reproducible and were similarly observed for PcRu [18] and (tbu) 4 PcRu [4], where they were assigned to the interaction of PcRu [18] and (tbu) 4 PcRu [4] with atmospheric oxygen.…”

Section: Introductionsupporting

confidence: 76%

“…Probably 5 also exists as a dimeric structure with a ruthenium-ruthenium double bond. The presence of such a ruthenium-ruthenium double bond has been reported for octaethylporphyrinato ruthenium [16,17], for PcRu [18,19] as well as for (tbu) 4 PcRu [4] and NcRu [5]. For metalloporphyrin dimeric complexes (only homometallic compounds) a molecular orbital (MO) diagram was described [20,21] The UV-vis spectrum of ((CH 3 ) 3 Si) 4 PcRu (5) recorded in dried and oxygen-free CH 2 Cl 2 under protected conditions shows a broad Q band at !…”

Section: Introductionmentioning

confidence: 84%

See 1 more Smart Citation

Synthesis and Properties of Tetrakis(trimethylsilyl)-phthalocyaninatoruthenium(II)

Dürr

Hanack

1999

J. Porphyrins Phthalocyanines

View full text Add to dashboard Cite

Tetrakis(trimethysilyl)phthalocyaninatoruthenium(II) (5) has been synthesized via the biaxially coordinated (( CH 3)3 Si )4 PcRu (3- Clpy )2 (2) complex by thermal decomposition of the axial ligands of 2. (( CH 3)3 Si )4 PcRu (5) was characterized by NMR, IR and UV-vis spectroscopy and elemental analysis. The trisubstituted (( CH 3)3 Si )3 PcRu (3- Clpy )2 (3) and disubstituted (( CH 3)3 Si )2 PcRu (3- Clpy )2 (4) complexes, formed as side products during the thermolysis of 2, could be isolated and characterized.

show abstract

Section: Introductionsupporting

confidence: 76%

Section: Introductionmentioning

confidence: 84%

Synthesis and Properties of Tetrakis(trimethylsilyl)-phthalocyaninatoruthenium(II)

Dürr

Hanack

1999

J. Porphyrins Phthalocyanines

View full text Add to dashboard Cite

show abstract

“…This agrees with LAXS investigations on the same system. [3] The existence of a RuϪRu double bond is also confirmed by measurement of the magnetic moment, which amounts to 2.54 µ B at room temperature. [7] Now the question arises as to whether the formation of dimers is restricted to PcRu or whether it is a common phenomenon of (phthalocyanine)ruthenium compounds.…”

Section: Introductionmentioning

confidence: 79%

Structural Investigations of Tetra- and Octasubstituted (Phthalocyanine)ruthenium Complexes by EXAFS Spectroscopy

Weber

Ertel

Reinöhl

et al. 2000

Eur. J. Inorg. Chem.

View full text Add to dashboard Cite

To obtain more structural information of (phthalocyaninato)ruthenium compounds, an EXAFS investigation was carried out on amorphous tBu4PcRu (1), tBu4PcRu(3‐Clpy)2 (2), PcRu(3‐Fpy)2 (3) and (C5H11O)8PcRu(3‐Clpy)2 (4). Structural models for the four compounds are deduced from the atomic distances determined around the metal centre. A dimeric structure was found for 1, while bisaxial arrangement of the ligands was shown for 2, 3 and 4, and the structural parameters were also determined.

show abstract

“…Thus, in an attempt to establish the type of cofacial arrangement of the molecular units in these solid materials, a structural investigation has been started by the use of the LAXS (large-angle X-ray scattering) technique [43], already applied successfully on substantially amorphous diphthalocyanine systems [44][45][46][47]. Measurements in a range of temperature (25-150°C) seem to indicate that water is lost without significantly affecting the overall solid state structure of the samples examined, and hence does not play a relevant role in determining the contacts between adjacent macrocyclic units.…”

Section: Structural Information and Further Observationsmentioning

confidence: 99%

New classes of porphyrazine macrocycles with annulated heterocyclic rings

Angeloni

Ercolani

2000

J. Porphyrins Phthalocyanines

View full text Add to dashboard Cite

The present contribution summarizes the most recent results on the synthesis and chemical physical characterization of the new classes of porphyrazine macrocycles having annulated five- and seven-membered heterocyclic rings, i.e. tetrakis(thiadizole)porphyrazine, TTDPzH 2, tetrakis(selenodiazole)porphyrazine, TSeDPzH 2, tetrakis-2,3-(5,7dipheny-6H-1,4-diazepino)porphyrazine, Ph 8 DzPzH 2, and a number of their metal derivatives, prepared by using, respectively, 3,4-dicyano-1,2,5-thiadiazole, 3,4-dicyano-1,2,5-selenodiazole, and 5,7-diphenyl-2,3-dicyano-6H-1,4-diazepine as monomeric precursors. The available information indicates that, owing to the presence of electron rich and soft atoms ( S , Se ) inserted in the proximity of the porphyrazine core, the TTDPz and TSeDPz macrocycles, closely resembling their phthalocyanine analogues in terms of structural and electronic features and physical behaviour (solubility, thermal stability, vaporizability, etc.), might be promising new materials for applicative properties. Particularly interesting is the operated peripheral ring opening of the TSeDPz macroxycle leading to the formation of octaaminoporphyrazine, followed by its conversion to a tetrakis(pyrazino)porphyrazine. The macrocycles containing the Ph 8 DzPz skeleton, due to the presence of the external non planar diphenyldiazepine units, appear to exhibit a distinct physical behaviour, which can be probably modulated by appropriate alternative substitutions in the 5, 6, and 7 positions of the diazepine rings.

show abstract

Ruthenium Phthalocyanine: Structure, Magnetism, Electrical Conductivity Properties, and Role in Dioxygen Activation and Oxygen Atom Transfer to 1-Octene

Cited by 84 publications

References 3 publications

Synthesis and Properties of Tetrakis(trimethylsilyl)-phthalocyaninatoruthenium(II)

Synthesis and Properties of Tetrakis(trimethylsilyl)-phthalocyaninatoruthenium(II)

Structural Investigations of Tetra- and Octasubstituted (Phthalocyanine)ruthenium Complexes by EXAFS Spectroscopy

New classes of porphyrazine macrocycles with annulated heterocyclic rings

Contact Info

Product

Resources

About