Raman spectroscopy was used to investigate the structure of ion-irradiated
α-SiC single crystals at room temperature and
400 °C. Irradiations induce a decrease of the Raman line intensities related to crystalline
SiC, the appearance of several new Si–C vibration bands attributed to the
breakdown of the Raman selection rules, and the formation of homonuclear
bonds Si–Si and C–C within the SiC network. For low doses, the overall
sp3
bond structure and the chemical order may be almost completely conserved. By contrast,
the amorphous state shows a strong randomization of the Si–Si, Si–C and C–C bonds. The
relative Raman intensity decreases exponentially versus increasing dose due to the
absorption of the irradiated layer. The total disorder follows a sigmoidal curve, which is
well fitted by the direct impact/defect stimulated model. The chemical disorder expressed
as the ratio of C–C bonds to Si–C bonds increases exponentially versus the dose. A clear
correlation is established between the total disorder and the chemical disorder. The
increase of temperature allows the stabilization of a disordered/distorted state and a
limitation of damage accumulation owing to the enhancement of the dynamic
annealing.