In order to reasonably and efficiently evaluate the emergency response capability of the refining and chemical enterprises, the methodology system of the emergency response capability evaluation based on AHP-Fuzzy for the refining and chemical enterprises was proposed. All factors involved in emergency response capability were divided into six sub capabilities according to the fishbone diagram, and the evaluation index system was established based on the Analytic Hierarchy Process (AHP) theory. Through the numerical solution, the weight distribution of indexes for all hierarchies was determined. After determining the weight distribution of indexes, based on the fuzzy theory, the fuzzy comprehensive evaluation method of emergency response capability was proposed, the fuzzy evaluation language was quantified into the expert evaluation results, and realized the transformation from qualitative evaluation to the quantitative analysis. Furthermore, the 4-day working scheme matching the evaluation model was proposed. On this basis, the A, B and C refining and chemical companies were selected as the pilot enterprises, the emergency capabilities of the three enterprises were systematically evaluated. Moreover, the deficiencies of the established emergency response capability evaluation methodology system were systematically summarized, which formed a closed-loop system of positive and negative dynamic feedback and updates, so as to ensure the dynamic adaptability of the emergency response capability evaluation methodology system. The evaluation methodology system established in this paper could provide the theoretical support for improving the emergency management system and enhancing the emergency capability.