2019
DOI: 10.1039/c9dt00485h
|View full text |Cite
|
Sign up to set email alerts
|

Salen supported Al–O–CP and Ga–PCO complexes

Abstract: The synthesis and reactivity of salen supported OCP adducts of aluminium and gallium is reported.

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
2
1
1

Citation Types

3
37
0
6

Year Published

2020
2020
2024
2024

Publication Types

Select...
7

Relationship

0
7

Authors

Journals

citations
Cited by 34 publications
(46 citation statements)
references
References 49 publications
3
37
0
6
Order By: Relevance
“…Selected interatomic distances [Å] and angles [ ]: P1-C1 1.670(2), C1-O1 1.155 (3), C2-P1 1.870(2), C2-B1 1.580(2), C2-N1 1.270(2); P1-C1-O1 173.6(2), C2-P1-C1 96.67(9), B1-C2-P1 122.97(12), B1-C2-N1 120.34(15), P1-C2-N1 116.66 (13). (2), C1-N1 1.195(2), P1-B1 1.912(2); P1-C1-N1 167.50 (13), C1-P1-B1 101.81 (7). structure of 4a ( Fig.…”
Section: Reactivity Of 1 With Isocyanidesmentioning
confidence: 99%
See 3 more Smart Citations
“…Selected interatomic distances [Å] and angles [ ]: P1-C1 1.670(2), C1-O1 1.155 (3), C2-P1 1.870(2), C2-B1 1.580(2), C2-N1 1.270(2); P1-C1-O1 173.6(2), C2-P1-C1 96.67(9), B1-C2-P1 122.97(12), B1-C2-N1 120.34(15), P1-C2-N1 116.66 (13). (2), C1-N1 1.195(2), P1-B1 1.912(2); P1-C1-N1 167.50 (13), C1-P1-B1 101.81 (7). structure of 4a ( Fig.…”
Section: Reactivity Of 1 With Isocyanidesmentioning
confidence: 99%
“…Young sample tube and a Xenon arc lamp was used, the microwave power was 1 mW and frequency was 9.391 GHz with a modulation amplitude of 1.5 mT. (17), C1-O1 1.239(2), C1-C2 1.407(2), C2-C55 1.449(2), C2-P2 1.7872 (16), P1-B1 1.915(2), O2-B2 1.371(2); B1-P1-P2 108.05 (6), B1-P1-C1 109.32(8), P1-C1-O1 128.70 (13), P1-C1-C2 99.50 (11), O1-C1-C2 131.76 (16), C1-C2-P2 103.95 (11), C1-C2-C55 123.93(15), C2-P2-P1 77.15 (5), C2-P2-O2 103.38 (7), P2-O2-B2 125.73 (11).…”
Section: Conflicts Of Interestmentioning
confidence: 99%
See 2 more Smart Citations
“…5 More recently, Grützmacher and co-workers reported the first examples of aluminium (C) and gallium (D) phosphaethynolate complexes stabilised by salen ligands. 6 The aluminium complex displays O-coordination whilst the gallium analogue was isolated as the P-bound isomer, in keeping with the decreasing oxophilicity upon descending the group, which in turn favours binding via the phosphorus atom. The polydentate character of the salen ligand limits the further reactivity of these species, which behave indistinguishably from one another and in a comparable manner to ionic phosphaethynolate salts of the alkali and alkaline-earth elements.…”
mentioning
confidence: 89%