Optical 64-QAM transmitter using QPSK modulators in tandem driven by binary electrical signals is proposed. The proposed transmitter eliminates the need for complex electronics required for the generation of multiple-level signals and provides a Gray-coded constellation with high quality eye diagrams. The design could be scaled to higherorder QAM based on the user needs. Conclusion: We have presented a scalable, optical square 64-QAM transmitter using tandem QPSK modulators driven by binary electrical signals. The transmitter designs for 64-QAM have been simulated at 50 Gbaud using OptiSystem. The results demonstrated Gray-coded symbol constellations and high quality eye diagrams.