Assuming that the final state of hadronization takes place along the freezeout line, which is defined by a constant entropy density, the antiproton-to-proton ratios produced in heavy-ion collisions are studied in framework of the hadron resonance gas (HRG) model. A phase transition from quark-gluon plasma to hadrons, a hadronization, has been conjectured in order to allow modifications in the phase-space volume and thus in the single-particle distribution function. Implementing both modifications in the grand-canonical partition function and taking into account the experimental acceptance in the heavy-ion collisions, the antiproton-to-proton ratios over center-of-mass energies √ s ranging from AGS to RHIC are very well reproduced by the HRG model. Comparing with the same particle ratios in pp collisions results in a gradually narrowing discrepancy with increasing √ s. At LHC energy, the ALICE antiproton-to-proton ratios in the pp collisions turn to be very well described by the HRG model as well. It is likely that the ALICE AA-program will produce the same antiproton-to-proton ratios as the pp-one. Furthermore, the ratio gets very close to unity indicating that the matter-antimatter asymmetry nearly vanishes. The chemical potential calculated at this energy strengthens the assumption of almost fully matter-antimatter symmetry up to the LHC energy.