Comprehensive Coordination Chemistry II 2003
DOI: 10.1016/b0-08-043748-6/02004-1
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Scandium, Yttrium, and the Lanthanides

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Cited by 34 publications
(8 citation statements)
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“…This is consistent with their smaller ionic radii and their preference for eight coordination. It is true that Ln(H 2 O) 9 3+ is known in some crystals even for the heavier lanthanides . However, in such cases the Ln−OH 2 bond is greatly lengthened.…”
Section: Discussionmentioning
confidence: 99%
“…This is consistent with their smaller ionic radii and their preference for eight coordination. It is true that Ln(H 2 O) 9 3+ is known in some crystals even for the heavier lanthanides . However, in such cases the Ln−OH 2 bond is greatly lengthened.…”
Section: Discussionmentioning
confidence: 99%
“…The reason for this ongoing debate is due, at least in part, to a lack of experimental data on soft donor complexes of actinides. Transuranic actinides are not only very rare and difficult to work with but actinides and lanthanides are also hard Lewis acids and strongly oxophilic, making isolation and characterization of f-element soft donor complexes a challenge. While an impressive array of novel f-element soft donor complexes has been discovered in areas such as organoactinide chemistry or actinide–ligand multiple bonding, classical Werner-type complexes of f-elements with exclusively N-donor ligands are very rare because of the rigorous conditions often required to prevent O-donor ligands from bonding.…”
Section: Introductionmentioning
confidence: 99%
“…The coordination chemistry of lanthanide nitrates with phosphine oxides has been studied extensively , because of the potential application of such complexes to nuclear reprocessing. , The relative ease with which their secondary structure can be altered to enhance solvent extraction properties and their chemically robust nature facilitates application in chemically aggressive environments. The complexes Y(NO 3 ) 3 (Ph 3 PO) 3 and Y(NO 3 ) 3 (Ph 2 MePO) 3 have a pseudo mer -octahedral geometry (if the nitrates are considered as occupying a single coordination site) but a fac arrangement with a less sterically demanding ligand in Y(NO 3 ) 3 (Me 3 PO) 3 .…”
Section: Introductionmentioning
confidence: 99%