Hydrogen (H2) as an ecofriendly alternative
to fossil
fuels faces challenges in storing large capacities for extended transportation
due to its low volumetric energy density. Also, common large-scale
storage techniques for H2 are associated with high energy
consumption, which is potentially at odds with the environmental benefits.
The multiproduct H2 storage systems are associated with
enhancing efficiency and environmental sustainability, leading to
significant cost savings and minimizing waste production. In this
paper, an integrated system that cogenerates liquids H2 and biomethane is designed using low-temperature cascade refrigeration
processes, cryogenic-based biogas purification cycle, proton exchange
membrane (PEM) electrolysis, and organic Rankine plant. A two-stage
mixed refrigerant refrigeration process is employed for purifying
untreated biogas, liquefying biomethane, and precooling H2 generated by a PEM electrolyzer. Four H2 Joule-Brayton
refrigeration systems are used to liquefy H2 in the hybrid
system. This hybrid configuration purifies 2917 kg/h unrefined biogas
and uses 27.71 MW power to produce 416.6 kg/h liquid H2 and 674 kg/h liquid biomethane. The energy and exergy efficiencies
for the designed integrated process are calculated at 54.65% and 56.67%,
respectively. The system exergy analysis reveals that the electrolyzer
(77.94%), heat exchangers (10.61%), and compressors (5.69%) are the
principal equipment in exergy destruction. Pinch analysis is employed
to design heat exchanger networks and reduce energy consumption effectively.
According to the economic analysis, the investment return period and
the prime cost of H2 are 5.589 years and 3.539 USD/kgLH2, respectively. The parametric sensitivity analysis demonstrates
that lowering the electricity cost from 0.1 to 0.03 USD/kWh leads
to a decrease in the prime cost of liquid H2 and the investment
return period to 2.205 USD/kgLH2 and 4.251 years, respectively.
Moreover, increasing the outlet pressure of the turbo-expander in
the cryogenic refrigeration cycle from 100 to 220 kPa results in an
increase in exergy efficiency and net annual benefit to 56.67% and
13.89 MMUSD/year, respectively, and a reduction in the prime cost
of liquid H2 to 3.536 USD/kgLH2.