The contemporary demands for massive reductions in industrial pollution caused by the transport sector, especially in large urban agglomerations, compel local and national authorities to propose, develop, and implement programs and policies that have the ultimate goal of significantly reducing (or eliminating) pollution. The aim of this article is to provide a primary analysis of the effectiveness of Romanian government policies in terms of reducing pollution (CO2 emissions) caused by transportation (due to the “Rabla Plus” (RP) program, through which financial subsidies are granted for the purchase of a new plug-in hybrid electric vehicles (PHEVs) or battery electric vehicle (BEVs)). After analyzing the justification for the use of low-emission and electric vehicles in traffic (as a major solution to eliminate pollution), a comparative analysis of energy-efficient transport for Romania and Europe is presented in order to identify the directions in which it is necessary to develop and implement government policies specifically in Romania, considering a series of indicators chosen and considered by the authors to be important, including CO2 emissions compared with the size of the road infrastructure, the number of registered vehicles, the number of passengers transported, and the quantity of goods transported. With the identification of the ability of government programs to encourage the acquisition and use of low-emission and electric vehicles in traffic, the efficiency achieved is calculated in terms of the net CO2 emissions eliminated (average values of 1949.23 CO2 tons/year and 1.71 CO2 tons/vehicle). Furthermore, this aspect is also beneficial for analyses in terms of the economic costs involved (the associated costs are estimated to be 7034.17 EUR/ton of CO2 eliminated from the transportation sector), identifying new directions of action that are more cost-effective and sustainable and on which government policies should focus in the future.