This work aims at solving complex problems of the optimal scheduling model of active distribution network, teaching strategies are proposed to improve the global search ability of particle swarm optimization. Moreover, based on the improved Euclidean distance cyclic crowding sorting strategy, the convergence ability of Li Zhiquan algorithm is improved. With the cost and voltage indexes of the energy storage system of the distribution network as the goal, different optimized configuration schemes are constructed, and the improved HTL-MOPSO algorithm is adopted to find the solution. The results show that compared with the traditional TV-MOPSO algorithm, the proposed algorithm has better convergence performance and optimization ability, and has a lower economic cost. In short, the algorithm proposed can provide a basis for improving the optimization of active distribution network scheduling strategies.