“…During the past 20 years, there have been many reports and models on the formation of surface barrier and surface Fermi level pinning due to the existence of surface states. [1][2][3][4][5][6] In our previous reports, 7 we have investigated the energy band gap, the built-in electric fields, and the surface Fermi level positions of a series of In 1Ϫx Al x As surface intrinsic-n ϩ structures of different composition x and/or different undoped layer thickness at room temperature by photoreflectance. We found that over aluminum concentration of 0.42-0.57, the energy gap depends on the composition of the sample and the surface Fermi level is not pinned at midgap, as commonly believed, but instead varies, respectively, from 0.50 to 0.81Ϯ0.01 eV below the conduction band edge.…”