TiO 2 nanofiber film (TiO 2 NFF) with visible light scattering ability was successfully synthesized by an ethylene glycol-assisted hydrothermal method, Au nanoparticles (Au NPs) were then deposited on the surface of TiO 2 film using microwave-assisted chemical reduction process, and at last, Bi 2 MoO 6 /Au/TiO 2 ternary photocatalytic film was successfully synthesized via a simple alcohol-thermal method using Au/TiO 2 nanofilms as templates. The photocatalytic activities of as-fabricated samples were investigated by the oxidation of organic pollutants, like methylene blue (MB) and phenol, and the reduction of aqueous Cr(VI) under visible light. It shows that the Bi 2 MoO 6 /Au/TiO 2 composite displays a much higher visible-light-responsive photocatalytic performance compared to pure TiO 2 , Au/TiO 2 NFF, and Bi 2 MoO 6 /TiO 2 complex. The improved visible light photoactivity could be ascribed to the excellent light scattering structure of TiO 2 NFF, the surface plasmon resonance effect of Au NPs, and the highly effective separation of photogenerated electrons and holes through the Z-scheme Bi 2 MoO 6 /Au/TiO 2 system, in which Au NPs plays a key role in transmitting charges in the photocatalytic process. Keywords: Bi 2 MoO 6 /Au/TiO 2 , light scattering, nano-fiber film, photogenerated electrons