Screening of Metal−Organic Frameworks for Carbon Dioxide Capture from Flue Gas Using a Combined Experimental and Modeling Approach

Yazaydın, A. Özgür; Snurr, Randall Q.; Park, Tae Hong; Koh, Kyoungmoo; Liu, Jian; LeVan, M. Douglas; Benin, Annabelle I.; Jakubczak, Paulina; Lanuza, Mary; Galloway, Douglas B.; Low, John J.; Willis, Richard R.

doi:10.1021/ja9057234

Cited by 841 publications

(692 citation statements)

References 25 publications

Supporting

Mentioning

659

Contrasting

Unclassified

Order By: Relevance

“…For example, MOFs can be produced with low densities (0.2-1 g cm -3 ), large surface areas (500-10,000 m 2 g -1 ), well-defined porous volume, good thermal and mechanical stabilities as well as with special chemical functionalities. These functions make MOFs a potential candidate for CO 2 adsorption (Uzun and Keskin 2014;Yazaydın et al 2009). Table 6 shows physical properties and adsorption capacity of different types of MOFs.…”

Section: Selective Adsorption Of Co 2 By Metal-organic Framework (Mofs)mentioning

confidence: 99%

Feasibility of CO2 adsorption by solid adsorbents: a review on low-temperature systems

Younas

Sohail

Leong

et al. 2016

Int. J. Environ. Sci. Technol.

200

View full text Add to dashboard Cite

In the last few decades of industrialization, the concentration of CO 2 in the atmosphere had increased rapidly. Different organizations have invested considerable funds in research activities worldwide for CO 2 capture and storage. To date, significant work has been done and various technologies have been proposed for CO 2 capture and storage. Both adsorption and absorption are promising techniques for CO 2 capture, but low-temperature adsorption processes using solid adsorbents are the prevailing technique nowadays. In this review paper, a variety of adsorbents such as carbonaceous materials, dry alkali metal-based sorbents, zeolites, metal-organic frameworks (MOFs) and microporous organic polymers (MOPs) have been studied. Various methods of chemical or physical modification and the effects of supporting materials have been discussed to enhance CO 2 capture capacity of these adsorbents. Low-temperature (\100°C) adsorption processes for CO 2 capture are critically analyzed and concluded on the basis of information available so far in the literature. All the information in CO 2 adsorption using different routes has been discussed, summarized and thoroughly presented in this review article. The most important comparative study of relatively new material MOFs and MOPs is carried out between the groups and with other sorbent as well.

show abstract

Section: Selective Adsorption Of Co 2 By Metal-organic Framework (Mofs)mentioning

confidence: 99%

Feasibility of CO2 adsorption by solid adsorbents: a review on low-temperature systems

Younas

Sohail

Leong

et al. 2016

Int. J. Environ. Sci. Technol.

200

View full text Add to dashboard Cite

show abstract

“…zeolites, activated carbons, carbon molecular sieves, MOFs, and so on, is becoming a challenging task in terms of efficiency and economical issues for carbon capture & storage technologies (CCS) [1][2][3][4]. Both the porous structure and the surface chemistry of these materials are critical parameters to be designed in order to achieve an optimum adsorption capacity.…”

Section: Introductionmentioning

confidence: 99%

High selectivity of TiC-CDC for CO2/N2 separation

Silvestre-Albero

Rico-Francés

Rodríguez‐Reinoso

et al. 2013

Carbon

View full text Add to dashboard Cite

A series of carbide-derived carbons (CDC) have been prepared starting from TiC and using different chlorine treatment temperatures (500ºC-1200ºC). Contrary to N 2 adsorption measurements at -196ºC, CO 2 adsorption measurements at room temperature and high pressure (up to 1 MPa) together with immersion calorimetry measurements into dichloromethane suggest that the synthesized CDC exhibit a similar porous structure, in terms of narrow pore volume, independently of the temperature of the reactive extraction treatment used (samples synthesized below 1000ºC). Apparently, these carbide-derived carbons exhibit narrow constrictions were CO 2 adsorption under standard conditions (0ºC and atmospheric pressure) is kinetically restricted. The same accounts for a slightly larger molecule as N 2 at a lower adsorption temperature (-196ºC), i.e. textural parameters obtained from N 2 adsorption measurements on CDC 2 must be underestimated. Furthermore, here we show experimentally that nitrogen exhibits an unusual behavior, poor affinity, on these carbide-derived carbons. CH 4 with a slightly larger diameter (0.39 nm) is able to partially access the inner porous structure whereas N 2 , with a slightly smaller diameter (0.36 nm), does not. Consequently, these CDC can be envisaged as excellent sorbent for selective CO 2 capture in flue-gas streams.

show abstract

“…The regeneration energy cost to utilize these porous materials for CO 2 capture by the implementation of temperature swing adsorption, pressure swing adsorption (PSA) and vacuum swing adsorption is significantly lower than the abovementioned alkanolamine technology. More importantly, the rapid development over the past decade in this research field to target some porous MOFs for their extremely high uptake of CO 2 at high pressure 11,12 and to immobilize functional sites, such as open metal sites [13][14][15][16][17][18][19][20][21][22][23] , -NH 2 and -OH organic sites into the pore surfaces to enhance their interactions and thus enforce their efficient CO 2 separation selectivity have principally ensured the feasibility of porous MOFs for CO 2 capture [24][25][26][27][28][29][30][31][32][33][34][35][36][37][38] .…”

mentioning

confidence: 99%

Microporous metal-organic framework with potential for carbon dioxide capture at ambient conditions

et al. 2012

View full text Add to dashboard Cite

Screening of Metal−Organic Frameworks for Carbon Dioxide Capture from Flue Gas Using a Combined Experimental and Modeling Approach

Cited by 841 publications

References 25 publications

Feasibility of CO2 adsorption by solid adsorbents: a review on low-temperature systems

Feasibility of CO2 adsorption by solid adsorbents: a review on low-temperature systems

High selectivity of TiC-CDC for CO2/N2 separation

Microporous metal-organic framework with potential for carbon dioxide capture at ambient conditions

Contact Info

Product

Resources

About