Wettability is a
main component that determines multiphase
flow
characteristics in a porous medium. Altering the wettability of a
rock has a wide range of applications in the field of geosystems engineering,
such as enhanced oil recovery, improving gas well deliverability,
and geological CO2 sequestration. Considering how injectivity
in many field water-alternating-gas (WAG) processes is lower than
expected, wettability alteration is especially suitable to address
the reduction in relative permeability encountered during water injection.
Several methods for injectivity improvement exist, including the use
of surfactants, nanoparticles, salts, and alkalis. Using silanes to
modify wettability has been a prominent technique in surface chemistry
for decades but has very rarely been applied to porous mineral rocks,
especially carbonates. This work explores the use of silanes to render
sandstone and limestone surfaces more hydrophobic, thereby reducing
gas blockage that causes injectivity loss. Contact angle measurements
were taken and showed good wettability alteration away from water
wet, exhibiting contact angles well above 90°, regardless of
treatment conditions. Centrifuge tests were carried out, and the resulting
residual fluid saturations and capillary pressure curves proved that
the treatment is also effective on the pore scale. Corefloods conducted
in sandstone and limestone cores showed a 45 and 65% increase in water
relative permeability after WAG cycles after treatment, respectively.
This translates directly to improvements in injectivity based on this
treatment method.