2023
DOI: 10.1002/ange.202316385
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Sculpting Mesoscopic Helical Chirality into Covalent Organic Framework Nanotubes from Entirely Achiral Building Blocks

Xinlin Zha,
Guilin Xu,
Niaz Ali Khan
et al.

Abstract: The diversification of chirality in covalent organic frameworks (COFs) holds immense promise for expanding their properties and functionality. Herein, we introduce an innovative approach for imparting helical chirality to COFs and fabricating a family of chiral COF nanotubes with mesoscopic helicity from entirely achiral building blocks for the first time. We present an effective 2,3‐diaminopyridine‐mediated supramolecular templating method, which facilitates the prefabrication of helical imine‐linked polymer … Show more

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