Seaweed Superheroes: Cystoseira barbata-Incorporated Electrospun Fibers for Lead Ion Sequestration

Abstract

The efficient removal of lead ions at low concentrations is paramount in combating the significant threat posed by water pollution resulting from industrial activities and population growth. In this study, electrospun C. barbata/PAN fibers were developed to efficiently remove lead(II) ions from water. The morphology, structure, and mechanical properties of the fibers were examined, highlighting that the augmentation of the surface area through the conversion of C. barbata into the polymer fibers facilitates increased metal bonding sites during sorption. C. barbata/PAN fibers exhibited superior characteristics, including higher surface area, smaller pore size, and increased pore volume, compared to powdered C. barbata. The effects of factors such as shaking time, algae percentage, sorbent amount, pH, metal concentration, and temperature on Pb(II) sorption were investigated by the batch method. At an initial ion concentration of 100 μg L −1 and pH 4.0, C. barbata (5 wt %)/PAN fiber demonstrated a notable sorption efficiency of 89−90% (270 μg/g) after 60 min. The equilibrium data align with the Freundlich and Dubinin−Radushkevich isotherm models, whereas the pseudo-secondorder kinetic model provides the most suitable description. The characterization of fibers after sorption revealed that carboxyl, hydroxyl, and sulfonyl groups play an active role in Pb(II) sorption.