2005
DOI: 10.1039/b506369h
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Second generation N-heterocyclic carbene–Pt(0) complexes as efficient catalysts for the hydrosilylation of alkenes

Abstract: A new class of benzimidazolylidene carbene-Pt(0) complexes was developed and used to efficiently catalyse the hydrosilylation of alkenes.

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Cited by 98 publications
(45 citation statements)
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“…Since then, the impact of NHCs and the related diaminocarbenes in organometallic chemistry has been unquestionable. [4][5][6][7][8] They [9] have been used in several metal-based catalysts for a large variety of reactions such as hydrogenations, [10,11] hydrosilylations, [12,13] olefin metathesis, [14][15][16][17] and C-C coupling reactions. [18][19][20][21][22] The large number of applications is due in part to the fact that complexes of these ligands are kinetically robust towards decomposition reactions.…”
Section: Introductionmentioning
confidence: 99%
“…Since then, the impact of NHCs and the related diaminocarbenes in organometallic chemistry has been unquestionable. [4][5][6][7][8] They [9] have been used in several metal-based catalysts for a large variety of reactions such as hydrogenations, [10,11] hydrosilylations, [12,13] olefin metathesis, [14][15][16][17] and C-C coupling reactions. [18][19][20][21][22] The large number of applications is due in part to the fact that complexes of these ligands are kinetically robust towards decomposition reactions.…”
Section: Introductionmentioning
confidence: 99%
“…Thus, although they have the topology of unsaturated NHCs, they show a reactivity typical of saturated carbenes. [11,13] [a] Ege University, Department of Chemistry, Bornova, 35100 Izmir, Turkey [b] We have tried to improve the catalytic activity of rhodium(I) complexes bearing ferrocenylphosphanyl-NHC ligands. Indeed, ferrocenyl-substituted NHCs are a class of ligands that has been little developed and has a great potential in both asymmetric and non-asymmetric catalysis.…”
Section: Introductionmentioning
confidence: 99%
“…The ligand, N,N -bis-neopentylbenzimidazolin-2-ylidene, is reported to have its carbene carbon atom dislodged from the plane of the imidazole ring by 20.7(11) and 19.0(11) pm (two crystallographically different molecules in the asymmetric unit), respectively. A recent search of the CCSD reveals that such a dislocation is very rare for coordinated carbene ligands and if it occurs is limited to a few pm [9,[79][80][81][82][83]. However, for the higher homologues, N-heterocyclic silylenes NHSi [84][85][86][87][88][89] and germylenes NHGe [26,90,91] the occurrence is far more frequent and appears to be the rule for annelated NHSi and NHGe.…”
Section: Complexes With Bent Nhcmentioning
confidence: 96%