Abstract. Classical homological algebra studies chain complexes, resolutions, and derived functors in additive categories. In this paper we define higher order chain complexes, resolutions, and derived functors in the context of a new type of algebraic structure, called an algebra of left cubical balls. We show that higher order resolutions exist in these algebras, and that they determine higher order Ext-groups. In particular, the E m -term of the Adams spectral sequence (m > 2) is such a higher Ext-group, providing a new way of constructing its differentials.