Secondary Metabolites from Mexican Species of the Tribe Senecioneae (Asteraceae)

Vivar, Alfonso Romo de; Pérez-Castorena, Ana-Lidia; Arciniegas, Amira; Villaseñor, José Luís

doi:10.29356/jmcs.v51i3.1347

Cited by 5 publications

References 64 publications

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14-Angeloyloxycacalohastine fromPsacalium peltatum

Rojano-Vilchis¹,

Hernández‐Ortega²,

Jiménez-Estrada³

et al. 2012

Acta Cryst E

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The title compound [systematic name: (9-methoxy-3,5-dimethyl-5,6-dihydronaphtho[2,3-b]furan-4-yl)methyl 2-methylbut-2-enoate], C21H24O4, was isolated from matarique, or Psacalium peltatum (Kunth). The structure is almost planar. The angeloyloxy group makes an angle of 62.08 (2)° with the furanoeremophilane skeleton. The carbonyl O atom is disordered between two positions with a 76:24 ratio. The molecules in the crystal are joined by very weak C—H—O interactions in the ac plane.

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14-Angeloyloxycacalohastine fromPsacalium peltatum

Rojano-Vilchis¹,

Hernández‐Ortega²,

Jiménez-Estrada³

et al. 2012

Acta Cryst E

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Juvenomimetic and Insecticidal Activities ofSenecio salignus(Asteraceae) andSalvia microphylla(Lamiaceae) onSpodoptera frugiperda(Lepidoptera: Noctuidae)

Romo-Asunción

Ávila-Calderón

Ramos-López

et al. 2016

Florida Entomologist

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Plant extracts can be used as an alternative to synthetic insecticides for the control of insect pests. Based on this knowledge, juvenomimetic and insecticidal activities of n-hexane extracts of the aerial parts of Senecio salignus DC. (Asteraceae) and Salvia microphylla Kunth (Lamiaceae) collected in Mexico were evaluated against 1st instar larvae of Spodoptera frugiperda Smith & Abbot (Lepidoptera: Noctuidae). Senecio salignus extract showed insecticidal activity at 500 ppm, resulting in larval mortality of 52.5% and pupal mortality of 62.5%. Salvia microphylla extract at the same concentration caused larval mortality of 65.0% and pupal mortality of 82.5%. The LC50 was 440 ppm for S. salignus extract and 456 ppm for S. microphylla extract based on the total larval period. The juvenomimetic activity of S. salignus extract at 500 ppm increased the duration of the larval period to 17.3 d and of the pupal period to 1.4 d. It also reduced pupal weight by 34.7% with respect to the control (241 mg). For S. microphylla extract at 500 ppm, the duration of the larval and pupal periods were increased by 2.0 and 12.1 d, respectively, and the pupal weight was reduced by 14.1% with respect to the control (243 mg). The major compounds of S. salignus extract were γ-sitosterol, palmitic acid, lupeol, and β-amyrin, and those of S. microphylla extract were oleic acid, γ-sitosterol, (Z,Z,Z)-9,12,15-octadecatrien-1-ol, and palmitic acid. These results indicate that both extracts have potential to be used to control S. frugiperda due to their juvenomimetic and insecticidal activities.

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Secondary metabolites in Viguiera (Compositae, Heliantheae, Helianthinae) and segregated genera. A review of their biological activities with chemotaxonomic observations

et al. 2022

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Background: The first monograph of the genus Viguiera was published in 1918 by Blake, including about 141 species. Schilling & Panero based on studies of molecular sequences of nuclear Internal Transcribed Spacer and External Transcribed Spacer, as well as cpDNA, proposed to reclassify the genus, relocating its species in at least other nine genera. Question: Is it possible to identify distinctive patterns between the species of the new classification of Viguiera s. l. and the results of the chemical studies reported? Species considered: Sixty-seven species within the wide Viguiera circumscription with chemical studies and biological activities reported. Results: The species of the genus Viguiera synthesize terpenoids represented mainly by sesquiterpene lactones and diterpenes, with triterpenes, polyacetylenes, volatile terpenoids and flavonoids also present. The main types of secondary metabolites were present in the studied species, although some compounds were more frequent than others in some clades. Conclusion: Germacrolides, heliangolides, furanoheliangolides, tetracyclic diterpenes and flavonoids are the main constituents of Viguiera and segregated genera. Some interesting chemotaxonomic relationships are noted. Nevertheless, nondistinctive clear patterns were observed between clades and chemical groups. These results may be a consequence of the reported chemical studies of the species of Viguiera s. l., which have not agreed on objetives or methodologies.

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Secondary Metabolites from Mexican Species of the Tribe Senecioneae (Asteraceae)

Cited by 5 publications

References 64 publications

14-Angeloyloxycacalohastine fromPsacalium peltatum

14-Angeloyloxycacalohastine fromPsacalium peltatum

Juvenomimetic and Insecticidal Activities ofSenecio salignus(Asteraceae) andSalvia microphylla(Lamiaceae) onSpodoptera frugiperda(Lepidoptera: Noctuidae)

Secondary metabolites in Viguiera (Compositae, Heliantheae, Helianthinae) and segregated genera. A review of their biological activities with chemotaxonomic observations

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