As urban populations continue to expand, the need for efficient and sustainable metro systems has become increasingly pressing. Traditional energy management methods, while somewhat effective, often fall short in fully utilizing the potential of regenerative braking systems within metro networks. These conventional approaches, which rely heavily on centralized control and energy storage systems, encounter scalability, security, and transparency limitations. Additionally, inefficient management of energy recovery data can result in significant energy losses and higher operational costs. In response to these challenges, this study proposes a blockchain-based solution utilizing Proof-of-Work (PoW) algorithms to optimize energy recovery, particularly during electric braking in metro systems. The developed model securely and transparently validates energy recovery events in real-time, eliminating the need for centralized oversight. By customizing the PoW algorithm, we achieved a balance between computational efficiency and strong security, making this solution scalable and practical for large metro networks. Initial simulations demonstrated a 12-15% improvement in energy recovery efficiency and a 10% reduction in operational costs compared to traditional systems. Furthermore, the comparison between net energy gains and the energy expended by the PoW process highlights the transformative potential of blockchain technologies in metro transportation, offering a pathway to more sustainable and environmentally friendly urban mobility solutions.