The unbalanced distribution of resource and consuming centers in China has prompted the AC/DC hybrid transmission technology. The maintenance scheduling of an AC/DC hybrid transmission network is the key technology to ensure its safety and reliability. In this study, the mutual influence mechanism of an AC/DC system in a maintenance period was analyzed in detail. The overhead transmission line and transformer are key equipment within an AC/DC hybrid transmission network, and an optimization model of the key equipment maintenance scheduling was established. The objective of the model was to improve the system reliability during the maintenance scheduling. By considering the constraints of maintenance cost, maintenance resources, and maintenance workload, the maintenance scheduling of overhead transmission lines and transformer branches was obtained. The over-limit situation of power flow and the weakness of the system during the maintenance period was evaluated. The “double-layer substitution method” was adopted to convert the nonlinear constraints into its bilinear formulation such that it could then be solved. The random number sampling method was used to quantify the system reliability, and the commercial optimization software was used to solve the optimized scheduling. Based on the improved IEEE RTS-79 system and the Hubei Province electrical system, the simulation results showed the effectiveness of the proposed method.