Recently, substantial investigations were developed on a polyvinyl chloride (PVC)-carbon fiber-reinforced polymer (CFRP) confined concrete (PFCC) structure owing to its superior mechanical behavior and durability. However, a convenient and effective joint configuration between the PFCC columns and reinforced concrete (RC) beams still requires in-depth study. In the present work, the seismic performance of an RC beam to PFCC column exterior joint with steel tube connector (STC) is systematically studied. Eleven joint specimens are fabricated and tested, with the steel ratio of STC, reinforcement ratio of the frame beam, axial compression ratio, stirrup ratio of the joint and CFRP strips spacing as the design parameters. The experimental results, that is, 8 the failure modes, hysteretic response, ductility, strength, stiffness and energy dissipation, are analyzed. All specimens exhibit joint shear failure, although the joints with STC exhibit significantly better performance those of ordinary joint. In addition to reducing the axial compression ratio, the reinforcement ratio of the frame beam or increasing the stirrup ratio of the joint can also produce a positive effect. Furthermore, the numerical analysis of the exterior joints is performed; the calculated skeleton curves agree well with the test results, and additional parametric studies (i.e., the diameter, height and concrete strength of the joint) are carried out based on the verified numerical model.