“…The major challenge for laboratory experimental characterization for CCUS is performing the test at in-situ representative pressure and temperatures while accounting for the solubility between the supercritical CO2 (SC-CO2) and water and the properties of the SC-CO2 [12]. There have been multiple studies aimed at characterizing the fluid substitution phenomenon in the lab space [12,14,15,16,17,18,19,20,21]. To replicate CO2 injection into the deep aquifers, most approaches involved injecting dry CO2 gas or CO2-brine solutions into brine saturated rock samples at varied conditions of temperature, pressure, and usually low effective stresses.…”