Selected-ion flow-tube mass-spectrometry (SIFT-MS) fingerprinting versus chemical profiling for geographic traceability of Moroccan Argan oils

Kharbach, Mourad; Kamal, Rabie; Mansouri, Mohammed Alaoui; Marmouzi, Ilias; Viaene, Johan; Cherrah, Yahia; Alaoui, Katim; Vercammen, Joeri; Bouklouze, Abdelaziz; Heyden, Yvan Vander

doi:10.1016/j.foodchem.2018.04.059

Cited by 47 publications

(46 citation statements)

References 37 publications

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“…The acidity parameter indicates the free acidity in terms of oleic acid in Argan oils, whereas the peroxide value measures the presence of primary oxidation products. Both K 232 and K 270 indicate the measure of the conjugated dienes and trienes formed by the Fas autoxidation (Kharbach et al, ).…”

Section: Resultsmentioning

confidence: 99%

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In vivo anti‐inflammatory response and bioactive compounds’ profile of polyphenolic extracts from edible Argan oil ( Argania spinosa L.), obtained by two extraction methods

et al. 2019

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The present work examined and assessed the in vivo anti-inflammatory effect of polyphenolic extracts from Moroccan edible Argan oils (Argania spinosa L.), extracted by two extraction processes: Hand pressing and mechanical pressing. Chemical properties, such as acidity, peroxide index, ultraviolet indices, total polyphenols composition, fatty acid composition, tocopherol composition, phenolic profiling, and sterol composition were studied. Then, the anti-inflammatory potential was determined by applying carrageenan, an induced paw edema test in rats. The results revealed an anti-inflammatory effect of edible Argan oil and indicated a higher efficiency of hand-pressed oil compared to mechanical-pressed oil, supporting its traditional use in human health, related to pain and inflammations. The chemical composition of these oils was evaluated, and total polyphenols, tocopherol composition, and some phenolic compounds were found highly concentrated in the hand-pressed oil. Practical applicationsThe present study highlights and compares the in vivo anti-inflammatory effect of polyphenolic compounds, extracted from Argan oil by two processes (hand and mechanical extraction). The study demonstrated the better quality of hand-pressed oil over mechanically pressed, supporting the traditional uses of this oil in treating several inflammations and pain-related situations. Moreover, the edible Argan oil may be introduced as a regular diet and food ingredient.

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Section: Resultsmentioning

confidence: 99%

“…These wide intervals might relate particularly to the Argan oil extraction process (mechanical or HP) (Matthäus et al, ). Both MUFA/PUFA and PUFA/SFA ratios were investigated in order to assess the nutritional value and the quality of both oils (Kharbach et al, ). The results showed good similarity for the two ratios in the MP and HP oils.…”

Section: Resultsmentioning

confidence: 99%

In vivo anti‐inflammatory response and bioactive compounds’ profile of polyphenolic extracts from edible Argan oil ( Argania spinosa L.), obtained by two extraction methods

et al. 2019

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“…48 Another study also examined the effectiveness of SIFT-MS vs chemical profiling to classify 95 extra-virgin Argan oils originating from five Moroccan Argan forest locations. 49 In both studies, the authors found the full scan option of SIFT-MS to be a sensitive and effective differentiator of geographic origin.…”

Section: Edible Oilsmentioning

confidence: 99%

“…More recently, SIFT‐MS combined with chemometrics has been used to authenticate the geographic origin labelling of 130 virgin olive oils from six different olive‐growing regions around the Mediterranean . Another study also examined the effectiveness of SIFT‐MS vs chemical profiling to classify 95 extra‐virgin Argan oils originating from five Moroccan Argan forest locations . In both studies, the authors found the full scan option of SIFT‐MS to be a sensitive and effective differentiator of geographic origin.…”

Section: Current Applications Of Sift‐ms In Food Aroma Analysismentioning

confidence: 99%

“… Increased use of SIFT‐MS data (whether targeted or SCAN mode) combined with multivariate statistics to provide rapid origin and quality screening. Examples presented here include the very recent publications on high‐throughput origin determination of Argan and olive oils. SIFT‐MS has potential to provide on‐line or high‐throughput flavour analysis correlations with sensory analysis, as illustrated by the work on Parmesan and beef On‐line monitoring to optimize product flavour during processing and avoid defects, as demonstrated by Barringer and co‐workers for tomato, cocoa, swiss cheese and coffee …”

Section: Concluding Remarks and Future Directionsmentioning

confidence: 99%

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Comprehensive odorant analysis for on‐line applications using selected ion flow tube mass spectrometry (SIFT‐MS)

Langford¹,

Padayachee²,

McEwan

et al. 2019

Flavour & Fragrance J

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Selected ion flow tube mass spectrometry (SIFT‐MS) is a direct mass spectrometry technique developed for volatile organic compound (VOC) analysis. In this comprehensive review of the SIFT‐MS flavour literature, its flexibility and utility are evident. SIFT‐MS has found wide application in the analysis of formation and release of odorants in fruits, vegetables, nuts, and seeds – including flavour and sensory optimization during cooking. Dairy products and poultry, red meat, and seafood also comprise a significant number of studies across processing, sensory, and shelf‐life studies. Edible oils, initially investigated for flavour and oxidative status, have recently been very successfully classified according to origin using a combined chemometrics and SIFT‐MS approach. Other recent developments – across different food groups – have been growth in applications to packaging (including meats in modified atmosphere packaging), and correlations of SIFT‐MS data with various types of sensory testing. The continuing growth of food odorant publications indicates that the SIFT‐MS technique has a significant role to play in understanding and managing favourable and unfavourable aroma formation in both academia and industry.

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Microwave Plasma Systems in Optical and Mass Spectrometry

Jankowski

Reszke²

2023

Encyclopedia of Analytical Chemistry

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Over the last decade, a revolutionary progress in both the instrumentation and the application of microwave plasma (MWP) systems for optical and mass spectrometry is observed. In this article, the current status of these systems is comprehensively reviewed and updated to 2022 to provide the reader with an advanced understanding of the theory, practices, and instrumentation associated with MWP‐based spectrometric techniques. Diverse MWP devices that can serve as atomizers, and radiation or ionization sources for various spectrometric techniques are all discussed and classified according to their fundamental microwave features and power coupling mode. Two basic MWP types constitute electrode‐operating capacitively coupled microwave plasmas (CMPs) and electrodeless microwave‐induced plasmas (MIPs). The recent development of the brand new devices such as microwave inductively coupled plasmas, rotating field MWPs, and microwave micro‐discharges is also discussed. In addition, so‐called tandem plasma sources that are a combination of MWP with another type of plasma are briefly commented on. An introduction to the various sampling techniques that can cope with MWPs such as hydride generation (HG), chemical vapor generation (CVG) and photochemical vapor generation (PCVG) for gaseous samples, solution nebulization for liquids, and dry aerosol generation techniques [electrothermal vaporization (ETV), spark (SA), laser ablation (LA), direct vaporization and ionization (DI), and continuous powder introduction (CPI)] for solids are presented highlighting their relative merits and demerits. Also, recent advances in sampling of nanoparticles for time‐resolved measurements and single particle analysis are mentioned. Further, a broad range of MWP‐based optical and mass spectrometric techniques is covered. Optical emission spectrometric (OES) methods based on MWPs are reviewed because a considerable amount of research is presently being performed in this field. Even when much less reported in the literature, several nonemission spectrometric techniques are also discussed. The mass spectrometry (MS) techniques including both the elemental mass spectrometry with hot MWPs and a variety of molecular MS techniques utilizing either hot or cold MWPs are discussed. Advances in sample introduction strategies, instrument optimization, calibration methods, and applications of MWP analytical spectrometry are discussed in the following sections. Due to the diversity of MWP instrumentation and related spectrometric techniques, it is impracticable to treat equally all of these issues in this survey. For this reason, the discussion of analytical performance and practical use is focused on key MWP‐based spectrometric techniques that have been employed, alone or hyphenated, using commercial instrumentation. The review of routine determination of metals and metalloids in different categories of samples is focused to cover the application of nitrogen MWP Optical Emission Spectrometer. Extended capabilities by hyphenating microwave plasma optical emission spectrometry (MWPOES) and microwave plasma mass spectrometry (MWPMS) to various well‐known separation techniques such as gas or liquid chromatography, and also size‐exclusion chromatography are discussed in brief. The application of advanced spectroscopic techniques in a wide range of environments focusing mainly, but not exclusively, on industrial and bioanalytical applications, its advantages, and limitations over other multielement instrumental techniques are discussed. Some of the areas where more developments can be expected in the future are suggested.

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Selected-ion flow-tube mass-spectrometry (SIFT-MS) fingerprinting versus chemical profiling for geographic traceability of Moroccan Argan oils

Cited by 47 publications

References 37 publications

In vivo anti‐inflammatory response and bioactive compounds’ profile of polyphenolic extracts from edible Argan oil ( Argania spinosa L.), obtained by two extraction methods

In vivo anti‐inflammatory response and bioactive compounds’ profile of polyphenolic extracts from edible Argan oil ( Argania spinosa L.), obtained by two extraction methods

Comprehensive odorant analysis for on‐line applications using selected ion flow tube mass spectrometry (SIFT‐MS)

Microwave Plasma Systems in Optical and Mass Spectrometry

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