Selected ion storage versus tandem MS/MS for organochlorine pesticides determination in drinking waters with SPME and GC-MS

Lara-Gonzalo, Azucena; Sánchez-Uría, J.E.; Segovia-García, Eva; Sanz‐Medel, Alfredo

doi:10.1080/03067319.2010.533766

Cited by 5 publications

(3 citation statements)

References 25 publications

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“…The coefficient of determination (R 2 ) ranged between 0.994 and 1 as reported in Table 2. These results were similar and even better than those reported in the literature [11,12,21,25].…”

Section: Methods Performance and Validationsupporting

confidence: 91%

“…For optimization, the analysis was done in triplicate. The impact of ionic strength was not investigated in the optimization process throughout this study since the addition of salt to the sample revealed a dramatic decrease in the response and sensitivity of certain compounds [11,12].…”

Section: Optimization Of Spme Parametersmentioning

confidence: 99%

“…This system is distinguished by its high selectivity and capability to achieve low detection limits and mass resolution; thus, making it suitable for the analysis of pesticide residues from various chemical groups [11]. Moreover, the ability of the MS detector to perform tandem mass spectrometry (MS/MS) promotes the analysis of pesticides in the low picogram levels, even in the presence of interferences, by reducing background noise significantly [12]. Due to the low levels of pesticides in environmental matrices, their diversity and different physicochemical characteristics [13], their detection requires the application of a fast, reliable, green and cost-effective pre-concentration technique [14,15].…”

Section: Introductionmentioning

confidence: 99%

See 2 more Smart Citations

Optimization of a DI-SPME-GC–MS/MS method for multi-residue analysis of pesticides in waters

Jabali

Millet

El-Hoz

2019

Microchemical Journal

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“…The coefficient of determination (R 2 ) ranged between 0.994 and 1 as reported in Table 2. These results were similar and even better than those reported in the literature [11,12,21,25].…”

Section: Methods Performance and Validationsupporting

confidence: 91%

Section: Optimization Of Spme Parametersmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

Optimization of a DI-SPME-GC–MS/MS method for multi-residue analysis of pesticides in waters

Jabali

Millet

El-Hoz

2019

Microchemical Journal

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Management of POPs: A Caribbean Perspective

Chicas

Valladarez

Carrias

et al. 2021

Emerging Contaminants and Associated Treatment Technologies

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Simultaneous analysis of organochlorine pesticides and polychlorinated biphenyls in air samples by using accelerated solvent extraction (ASE) and solid-phase micro-extraction (SPME) coupled to gas chromatography dual electron capture detection

Mokbel

Dine

Elmoll

et al. 2016

Environ Sci Pollut Res

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An analytical method associating accelerated solvent extraction (ASE) and solid-phase micro-extraction (SPME) in immersion mode combined with gas chromatography dual electrons capture detectors (SPME-GC-2ECD) has been developed and studied for the simultaneous determination of 19 organochlorine pesticides (OCPs) and 22 polychlorinated biphenyls (PCBs) in air samples (active and XAD-2 passive samplers). Samples were extracted with ASE with acetonitrile using the following conditions: temperature, 150 °C; pressure, 1500 psi; static, 15 min; cycles, 3; purge, 300 s; flush, 100 %. Extracts were reduced to 1 mL, and 500 μL of this extract, filled with deionised water, was subject to SPME extraction. Experimental results indicated that the proposed method attained the best extraction efficiency under the optimised conditions: extraction of PCB-OCP mixture using 100-μm PDMS fibre at 80 °C for 40 min with no addition of salt. The performance of the proposed ASE-SPME-GC-2ECD methodology with respect to linearity, limit of quantification and detection was evaluated by spiking of XAD-2 resin with target compounds. The regression coefficient (R (2)) of most compounds was found to be high of 0.99. limits of detection (LODs) are between 0.02 and 4.90 ng m(-3), and limits of quantification (LOQs) are between 0.05 and 9.12 ng m(-3) and between 0.2 and 49 ng/sampler and 0.52 and 91 ng/sampler, respectively, for XAD-2 passive samplers. Finally, a developed procedure was applied to determine selected PCBs and OCPs in the atmosphere.

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Selected ion storage versus tandem MS/MS for organochlorine pesticides determination in drinking waters with SPME and GC-MS

Cited by 5 publications

References 25 publications

Optimization of a DI-SPME-GC–MS/MS method for multi-residue analysis of pesticides in waters

Optimization of a DI-SPME-GC–MS/MS method for multi-residue analysis of pesticides in waters

Management of POPs: A Caribbean Perspective

Simultaneous analysis of organochlorine pesticides and polychlorinated biphenyls in air samples by using accelerated solvent extraction (ASE) and solid-phase micro-extraction (SPME) coupled to gas chromatography dual electron capture detection

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