Atmospheric deposition is an important
source of trace elements
(TEs) to the Arctic, including both anthropogenic (e.g., Pb) and micronutrient
(e.g., Fe) metals. This study measured TE loadings, Pb isotopes, and
dissolution in aerosols collected at Alert, Nunavut, Canada, from
spring to summer of 2013 and 2014 and during the Canadian Arctic GEOTRACES
Cruises (GN02 and GN03) in the summer of 2015. The aerosol loadings
were 5–8 times higher and more enriched with anthropogenic
metals (Pb and Cd) in the spring than in the summer consistent with
the Arctic haze phenomenon. Pb isotopes reveal that Russia, Europe,
and China were the likely source regions of this pollution in spring.
Comparison of the Pb and Cd concentrations and Pb isotope data with
previous studies suggests that atmospheric pollution in the Canadian
Arctic has been relatively stable for the last couple of decades.
Dissolution experiments were also performed to estimate the fraction
of aerosol TEs that can potentially be dissolved and become bioavailable
in seawater. The minimum and maximum dissolution estimates for Fe
were 8 ± 5 and 65 ± 20%, respectively, which translate to
a potential input of 5–40 kT year–1 of dissolvable
Fe to the Canada Basin of the Arctic Ocean, comparable to the riverine
Fe input (10–20 kT year–1) from Mackenzie
River. Thus, aerosols could be an important Fe source to Arctic surface
waters, especially with decreasing sea ice coverage, changes in stratification
and in places far from shelf and river sources.