The stability of the high voltage arm resistors has a strong influence on the performance of the resistance high DC voltage divider. So by analyzing the main parameters that affect the resistor value change, including voltage coefficient, power coefficient and so on, a new matching method is proposed to make a high precision high DC voltage divider in this paper. Based on the principle of pairing the resistors and adjusting the big and small ones, a high precision high DC voltage divider could be made with the voltage variation less than 0.005%, even on the condition of using high voltage coefficient and power coefficient resistors.