Given a Lipschitz function f : {1, ..., d} N → R, for each β > 0 we denote by µ β the equilibrium measure of βf and by h β the main eigenfunction of the Ruelle Operator L βf . Assuming that {µ β } β>0 satisfy a large deviation principle, we prove the existence of the uniform limit V = lim β→+∞ 1 β log(h β ). Furthermore, the expression of the deviation function is determined by its values at the points of the union of the supports of maximizing measures. We study a class of potentials having two ergodic maximizing measures and prove that a L.D.P. is satisfied. The deviation function is explicitly exhibited and does not coincide with the one that appears in the paper by Baraviera-Lopes-Thieullen which considers the case of potentials having a unique maximizing measure.