Selective Allowance of Precipitation from Oversaturated Solution Using Surface Structures

Abstract

Precipitation is a well-known phenomenon commonly observed in salt ponds. However, it causes pipe clogging in industrial sites, which can be resolved by controlling the direction of precipitation. Herein, we propose a method to control the precipitation direction by changing the structures and properties of the solid surface. Bare, nanostructured, microstructured, and micro/nanostructured surfaces were immersed in the same saturated aqueous NaCl solution, and the heights at which precipitation occurred in the different specimens were compared. On bare and nanostructured surfaces, NaCl deposits as a flat layer on the surface, while on micro and micro/nanostructured surfaces, it forms a thick deposit in a direction perpendicular to the surface. When the same experiment was conducted on surfaces made by patterning different structural surfaces, the precipitates did not spread on the surface with microscale structures. We believe that this novel approach may prove useful in solving the problems caused by precipitation.