In recent years, there has been a great interest in new routes for depositing GaN films in the application of III-V semiconductors. We report herein on the deposition of highly crystalline GaN films by low-pressure MOCVD (in the low-temperature range of 500-700 °C and the pressure range of 77-177 mbar) using the single-source precursor (Et 2 GaNH 2 ) 3 . This process was investigated for a variety of substrates (Si(100) and polycrystalline Al 2 O 3 ) using a cold wall chemical vapor deposition reactor. The thickness of films grown under these conditions ranged from 6 to 8 µm, and the growth rates varied from 7 to 8 µm/h. Films deposited at lower temperatures (500-550 °C) had a pale yellowish color and were amorphous. At 600 °C slightly gray colored films were obtained, while above 650 °C highquality crystalline films were formed, which show diffraction patterns characteristic of the hexagonal wurtzite structure. The films are consistent with the 1:1 stoichiometry of GaN and have carbon and oxygen as impurities; however, cracks were not evident on the surface by SEM examination up to a magnification of 30 000. In contrast, samples of GaN deposited under high-vacuum conditions (up to 10 -2 mbar) have neither a 1:1 stoichiometry nor a smooth surface morphology. Atomic force microscopy, scanning electron microscopy, Auger electron microscopy, and energy-dispersive X-ray analyses were used for the study of the structure, composition, and morphology of the films.