Summary:
The patterns of absorption and translocation of 14C clopyralid commercially formulated as the acid, monoethanolamine salt, potassium salt, 2‐ethylhexyl ester and 1 ‐decyl ester were compared in Cirsium arvense and Polygonum convolvulus grown under three environmental regimes. Plants were grown under a 35% or 65% RH regime in silica sand maintained at 33% w/w moisture or under a water stress regime at 65% RH. Approxi mately 26,39,86,93 and 100% of the applied 14C‐activity from the 2‐ethylhexyl ester, acid, monoethanolamine salt, 1‐decyl ester and potas sium salt, respectively, were recovered 72 h after application to glass cover slips placed in the growth room. However, loss of applied 14C‐activity after application of the five formulations to both plant species was significant only for the 2‐ethylhexyl ester. Regardless of environmental regime, the acid was the most readily absorbed formulation. In contrast to the acid, the salts and esters were less readily absorbed. When the data were expressed as a percentage of absorbed radioactivity, there was no significant difference in translocation when the acid, monoethanolamine salt and potassium salt were compared. However, significantly smaller quantities of the absorbed 2‐ethylhexyl and 1‐decyl ester were exported from the treated leaf. These results indicate that once absorbed, the esters do not readily partition out of the cuticle, whereas the acid and two salts move into the symplast for subsequent translocation. When the results of the three environmental regimes were compared, the absorption of the monoethanolamine and potas sium salts were greatly reduced under low humi dity or water stress, whereas the acid and esters were not affected.