Selective flotation of fine-ingrained carbonate-fluorite ore in pulp of increased dispersion uniformity

2020

The article provides an assessment of the technological features of mature tailings from the processing of finely disseminated fluoritecontaining raw materials of the Yaroslavkaya Mining Company. The prospects for their secondary processing are considered. It has been established that the waste stored in various sectors of the enterprise’s tailings contain from 13 to 23% fluorite, 12-14% calcite. The characteristic is given to the technological features of raw materials. The fluorite grains present in the technogenic tailings are characterized by the presence of thin inclusions and veins of silicate minerals. An obstacle to the selective separation of minerals by the flotation method is the shielding coatings of the surface zone of mineral particles, formed from contact with reagents at the stage of primary ore processing and in the process of interaction with the water-air environment in the tailing dump. The ways of increasing the contrast of the adsorption properties of minerals are proposed. Important factors influencing the process of mineral selection, allowing to influence the quality characteristics of flotation of refractory secondary raw materials is fine grinding of the material in combination with a high degree of dilution of the pulp. The possibility of extracting concentrates with a CaF2 content of 95.2-95.6% with the recovery of fluorite in them of 57-60.7% is shown. The introduction of inter-cycle regrind of foam products into the operation scheme allows to reduce the content of silicone dioxide in concentrates to 0.98%, which meets the requirements of consumers.

Section: Materials and Research Methodsmentioning

confidence: 99%

Evaluation of the influence of the dispersion-sludge characteristics of the pulp on the beneficiation indicators of technogenic fluorite-containing tailings

Kienko

2020

“…With the content of CaF 2 in the concentrates amounting to 93.28-94.14%, the fluorite extraction was 60.26-61.75%. A further increase in the degree of grinding can lead to a decrease in technological parameters [5,6].…”

Section: Methodsmentioning

confidence: 99%

Study of the prospects for expanding the range of collectors in the flotation of fluorite from technogenic raw materials

Kiyenko

2020

The results of studies on the development of a technology for the extraction of fluorite concentrates from finely disseminated refractory technogenic raw materials from Primorsky deposits were presented. The account of the technological features of the stale tailings of the concentration plant of Yaroslavkaya Mining Company has been given. The necessity of fine grinding of the material and careful selection of reagent compositions providing the required flotation selectivity has been substantiated. The fundamental possibility of obtaining fluorite concentrates containing CaF2 up to 94% and more using several samples of collectors from the group of fatty acids has been established. Fatty acids of tall oil produced by Ust-Ilimsk timber processing complex and a mixture of fatty acids produced in India, branded MASOIL 1880, provide a sufficient level of flotation selectivity. The recovery of fluorite in an open enrichment cycle according to the scheme with seven cleanings of the foam product can be 61.85-63.84%. The use of collectors compositions promotes an increase in the selectivity of the adsorption of reagents, which is accompanied by an increase in the selectivity of their action in comparison with the results obtained with the dosage of certain brands of the tested reagents into the flotation process. The extraction of fluorite into a concentrate obtained using a combination of tall oil and MASOIL-S fatty acids in a 1:1 ratio was 59.55-66.27% with a content of 95.6-94.23% CaF2 in it, respectively.

“…In the cycle of experiments with a further reduction in the size of the boundary grain and the identification of the effect of fineness of grinding on the flotation indices, it has been established that the optimum grinding size corresponds to a content of the -0.044 mm class of not less than 95-97%. Further increase in the fineness of grinding leads to a decrease in technological indices, which is caused by increasing slurry fractions volumes [10][11][12].…”

Section: Materials and Methods Of The Researchmentioning

confidence: 99%

The prospects for secondary processing of tailings remained after the beneficiation of fluorite ores of Primorye Krai using a highly selective combination of reagents

Kienko

2018

The study of the composition and preparability of two samples of tailings dumped at the Yaroslavl Mining Company revealed the following contents: CaF2 - 15.2 and 20.7%, CaCO3 - 13.3 and 10.2%, and Zn - 0.49 and 0.38%. The volume of the stockpiled wastes is estimated at 30 million tons. The need for fine material grinding at the stage of preparation for flotation was shown, and the efficient fluorite concentration was possible with technical solutions found. The determined optimal parameters of the flotation acid-base condition provided neutralization of the negative influence of salts and slimes left by the previous processing cycle. It has been established that a mixture of ammonium and lignosulfonates was effective as a modifier. The extraction of sample 1 yielded 52% of fluorite extraction to the concentrates with 92.2-92.8% fluorite content, and more than 69% when beneficiating the sample 2. Upgrading of the concentrate quality is only possible through transferring to flotation tails of the most contaminated fluorite grains impregnated with silicate minerals, but this is followed by a significant extraction reduction. The concentration of sphalerite to a separate product occurs with low effectiveness. The inclusion of sulfide flotation in the circuit head can improve the fluorite cycle efficiency: extraction of CaF2 to the concentrates of FF-92 brand may reach 70%.