Functionally graded materials (FGMs) are compositionally gradient materials which were first proposed in Japan in 1984. [1] They have been suggested as a way of fabricating bulk materials with tailored properties because they can achieve the controlled distribution of the desired characteristics within the same bulk material. This FGM can be applied for engineering parts instead of coated materials. However, careful selection of the component materials, particularly the reinforcement, is required to reliably achieve a high performance from the FGM. Carbon nanotubes (CNTs), which have a unique combination of excellent mechanical, electrical, and thermal properties, have become a hot property in the engineering materials field, since their discovery in Japan in 1991. [2,3] For this reason, CNT is a satisfactory candidate to be a reinforcement material for fabricating high quality FGMs.Extensive research on the fabrication and characterization of CNT-reinforced polymer, [4,5] ceramic, [6,7] and metal matrix [8,9] composites has been carried out but CNT gradient layer-reinforced FGMs have rarely been investigated. Recently, Estili et al. have reported that the CNT gradient layer in ceramic matrix composite materials fabricated by the spark plasma sintering process shows similar hardness results to the ceramic matrix. [10] Ke et al. studied the nonlinear free vibration of functionally graded CNT nanocomposite based on numerical results. [11] Shen and Zhang have reported the mechanical behavior of functionally graded CNT-reinforced composites in thermal environments by a micromechanical model. [12,13] Indeed, most investigations regarding functionally graded CNT-reinforced composite materials were based on numerical calculations or models.In the present study, we attempted to fabricate functionally graded CNT-reinforced metal matrix composite bulk materials by a powder metallurgy route and to then characterize these composites. Aluminum (Al) was utilized for the matrix material because its high specific strength and high ductility [14] combined with the CNT offers high performance of structural materials. In particular, extremely different characteristics in the same Al-CNT bulk materials (e.g., highly strengthened surfaces and highly enhanced ductility inside) can be achieved by the FGM concept. The various Al-CNT composite powders were prepared by a planetary ball milling process and then hot pressed in a layered structure. The FGM bulk obtained was analyzed, with a focus on the hardness of each CNT gradient layer. Moreover, microstructural observations, phase analyses, and density measurements were carried out, to develop a better understanding of the hardness behavior in the FGM bulk.
ExperimentalMultiwalled CNTs (Baytubes C150P, Bayer material science, purity 99.5%, diameter: 20 nm, length: 30 mm) and gas-atomized pure Al powder (ECKA Granules, purity 99.5%, mean particle size: 63 mm) were used as the starting materials. Homogeneously well dispersed CNT-Al composite powders containing 5, 10, and 15 vol% CNT were p...