Selective Oxidation of Alcohol to Valuable Aldehydes Using Water as a Promoter in a Photoelectrochemical Cell

Sun, Jialin; Wang, Binbin; Nie, Zunyan; Jia, Xin; Li, Chunxiao; Li, Mingjun; Zhao, Yingchun; Zhang, Xuekai; Wang, Bo; Xiao, Jingran

doi:10.1021/acs.langmuir.4c01453

Langmuir

2024

DOI: 10.1021/acs.langmuir.4c01453

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Selective Oxidation of Alcohol to Valuable Aldehydes Using Water as a Promoter in a Photoelectrochemical Cell

Jialin Sun,

Binbin Wang,

Zunyan Nie

et al.

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Selective Oxidation of Alcohols to Carbonyls Under Decatungstate‐Mediated Photoelectrochemical Conditions

Capucciati,

Baraglia,

Cassera

et al. 2024

Chemistry A European J

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The oxidation of alcohols to the corresponding carbonyl derivatives has been realized under photoelectrochemical conditions in the presence of tetrabutylammonium decatungstate (TBADT) as the homogeneous photocatalyst. The protocol can be applied to both primary and secondary, benzylic and aliphatic alcohols. The desired products are obtained selectively, skipping the need for purposely added chemical oxidants. An in‐depth study of photoelectrochemical conditions revealed that the protocol works best under amperostatic conditions in an undivided electrochemical cell irradiated with a 390 nm LED lamp. The comparison with analogous electrochemical and chemical oxidant‐promoted photocatalytic oxidations demonstrates the superior efficiency and selectivity of the hereby reported photoelectrochemical conditions.

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Selective Oxidation of Alcohols to Carbonyls Under Decatungstate‐Mediated Photoelectrochemical Conditions

Capucciati,

Baraglia,

Cassera

et al. 2024

Chemistry A European J

View full text Add to dashboard Cite

show abstract

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Selective Oxidation of Alcohol to Valuable Aldehydes Using Water as a Promoter in a Photoelectrochemical Cell

Cited by 1 publication

References 46 publications

Selective Oxidation of Alcohols to Carbonyls Under Decatungstate‐Mediated Photoelectrochemical Conditions

Selective Oxidation of Alcohols to Carbonyls Under Decatungstate‐Mediated Photoelectrochemical Conditions

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