Selective recognition of monohydrogen phosphate by fluorescence enhancement of a new cerium complex

Ganjali, Mohammad Reza; Hosseini, Morteza; Memari, Zahra; Faridbod, Farnoush; Norouzi, Parviz; Goldooz, Hassan; Badiei, Alireza

doi:10.1016/j.aca.2011.09.032

Cited by 53 publications

(16 citation statements)

References 31 publications

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“…The detection limit of this work achieved by fluorimetric and colorimetric method is 0.071 and 1.46 µmol L -1 , respectively, which is excellent compared with previous electrochemical reports [22,50,51]. Besides, the detection limit of present fluorimetric probe is comparable to that of the prior fluorimetric report [33]. A C C E P T E D M A N U S C R I P T…”

Section: Accepted Manuscriptsupporting

confidence: 71%

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Indigo Carmine-Cu complex probe exhibiting dual colorimetric/fluorimetric sensing for selective determination of mono hydrogen phosphate ion and its logic behavior

Tavallali

Deilamy‐Rad

Moaddeli

et al. 2017

Spectrochimica Acta Part A: Molecular and Biomolecular Spectros

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Section: Accepted Manuscriptsupporting

confidence: 71%

“…Incorporation of transition metals in to the anion receptors can present some geometrical preference for anions in comparison with organic compounds [33].…”

mentioning

confidence: 99%

Indigo Carmine-Cu complex probe exhibiting dual colorimetric/fluorimetric sensing for selective determination of mono hydrogen phosphate ion and its logic behavior

Tavallali

Deilamy‐Rad

Moaddeli

et al. 2017

Spectrochimica Acta Part A: Molecular and Biomolecular Spectros

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“…Thus, GG was prepared in excellent yield (96%) using a nucleophilic addition of the corresponding Grignard derivative of aryl bromide (9) to the TBDMS-protected 3,6-dihydroxyxanthenone (10) 20 and subsequent dehydration with aqueous hydrochloric acid (Scheme 1). In this case, the tert-butyl group present in the final product fulfilled a dual role.…”

Section: Resultsmentioning

confidence: 99%

Rational design of a new fluorescent ‘ON/OFF’ xanthene dye for phosphate detection in live cells

et al. 2014

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A new fluorescein derivative with ON/OFF features, 9-[1-(4-tert-butyl-2-methoxyphenyl)]-6-hydroxy-3H-xanthen-3-one (Granada Green, GG), was designed and synthesised. The new dye has spectral characteristics similar to those of other xanthenic derivatives but shows a higher pK(a) value for the equilibrium between its neutral and anionic forms. In addition, GG undergoes the same phosphate-mediated excited state proton transfer (ESPT) reaction as other xanthenic derivatives, giving rise to fluorescence decay traces that are dependent on both the phosphate concentration and pH of the medium. The phosphate-mediated ESPT reaction was employed to detect changes in the phosphate concentrations in live, permeabilised MC3T3-E1 preosteoblasts at pH 7.35. Its high pK(a) value indicates that this new dye is more sensitive as an intracellular phosphate sensor than other previously tested dyes, as experimentally demonstrated by its ability to detect a wider range of phosphate concentrations in biomimetic media and by the increased ratio of the phosphate concentration/decay time.

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“…The use of phosphate sensors/receptors, coupled with optical detection has been researched quite extensively. The detection has normally been colorimetric (Tobey & Anslyn, 2003;Han & Kim, 2002) and luminescence/fluorescence (Yaqoob et al, 2004;Lin et al, 2006;Sun et al, 2008;Ganjali et al, 2011;Anzenbacher et al, 2000;Ojida et al, 2002Ojida et al, , 2004Hamachi, 2009;Sessler et al, 2003;Deetz & Smith, 1998;Du et al, 2008;Fabbrizzi et al, 2002). These methods have yielded detection limits varying from milligrams to micrograms per litre but which are higher than the much lower detection limits required for environmental applications.…”

Section: Optical Detection Methodsmentioning

confidence: 99%

Phosphomolybdenum Blue Detection – A Review of Characteristics, Achievements, Challenges and Future Prospects

Doku

Agbozo

Haswell

et al. 2020

gjs

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Phosphate detection in the environment (especially, water bodies) is very essential in view of its consequent pollution effects on eutrophication. Continuous monitoring of phosphate concentration (and phosphorus compounds in general) in water samples has been based on phosphomolybdenum blue formation coupled with spectrophotometric detection. Continuous flow injection analyses (FIA) are well known to present numerous advantages over batch methods. Furthermore, the development of on-chip micro-channel analytical (μFIA) systems begun and have gained much attention within the last two decades in view of the striking advantages over conventional FIA techniques. This paper reviews published information on detection of phosphomolybdenum blue in conventional systems as well as on micro-chip. It reports on the challenges encountered (interference from other complex anions), the achievements made so far (intereference removal by electrokinetic separation) and what the future holds (simultaneous determination).

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Selective recognition of monohydrogen phosphate by fluorescence enhancement of a new cerium complex

Cited by 53 publications

References 31 publications

Indigo Carmine-Cu complex probe exhibiting dual colorimetric/fluorimetric sensing for selective determination of mono hydrogen phosphate ion and its logic behavior

Indigo Carmine-Cu complex probe exhibiting dual colorimetric/fluorimetric sensing for selective determination of mono hydrogen phosphate ion and its logic behavior

Rational design of a new fluorescent ‘ON/OFF’ xanthene dye for phosphate detection in live cells

Phosphomolybdenum Blue Detection – A Review of Characteristics, Achievements, Challenges and Future Prospects

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