1993
DOI: 10.1021/ie00018a010
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Selective reduction of nitrogen oxides (NOx) by ammonia over honeycomb selective catalytic reduction catalysts

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Cited by 81 publications
(17 citation statements)
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“…Diffusion often limits the activity of the catalysts especially at high reaction rates, which are usually observed in NO SCR with NH 3 . In the case of traditional vanadia-based catalysts, the SCR reaction is strongly limited by gas-solid interface mass transfer and by slow intraparticle diffusion [8,9]. This ismost probably also the case for the Fe-ZSM-5 zeolite catalysts with channel dimensions within the range of small molecules.…”
Section: Introductionmentioning
confidence: 99%
“…Diffusion often limits the activity of the catalysts especially at high reaction rates, which are usually observed in NO SCR with NH 3 . In the case of traditional vanadia-based catalysts, the SCR reaction is strongly limited by gas-solid interface mass transfer and by slow intraparticle diffusion [8,9]. This ismost probably also the case for the Fe-ZSM-5 zeolite catalysts with channel dimensions within the range of small molecules.…”
Section: Introductionmentioning
confidence: 99%
“…4. The competitive adsorption between SO 2 and NH 3 may prevent transformation of CuO to CuSO 4 . As a result, the catalysts sulfated in the presence and absence of NH 3 show different SCR activities.…”
Section: Discussionmentioning
confidence: 99%
“…The worldwide trend towards the increasingly stringent emission levels has spurred research and development on cost-effective technologies capable of reducing NO x emission. Among them, selective catalytic reduction (SCR) of NO with NH 3 in the presence of oxygen is proven to be advantageous [1,2], and honeycomb V 2 O 5 /TiO 2 has been used for this process in industries due to its high activity and low flow resistance [3,4]. However, porous titania in anatase form required in the current practice was reported to be both difficult to prepare and physically weak [5].…”
Section: Introductionmentioning
confidence: 99%
“…In commercial practice in power plants most SCR reactors are hot-side, high dust installations. The SCR technology is based on the reduction of nitrogen oxide (NO) with ammonia (NH 3 ) [8]. In a side reaction, SCR catalysts are known to convert sulphur dioxide (SO 2 ) to sulphur trioxide (SO 3 ) .…”
Section: Selective Catalytic Reduction (Scr) Processmentioning
confidence: 99%