Selective Transport of Fe(III) Using Polyeugenol as Functional Polymer with Ionic Imprinted Polymer Membrane Method

Djunaidi, Muhammad Cholid; Jumina, Jumina; Siswanta, Dwi; Ulbricht, Mathias

doi:10.14233/ajchem.2015.19228

Cited by 13 publications

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“…There are three main strategies that can be used to synthesize MIM [3][4]: (1) sequential approach preparation of membrane from IIP S that had been prepared using conventional method; (2) simultaneous formation of IIP structure and membrane morphology; and (3) Sequential approach preparation of IIP using supporting membrane with morphology. have synthesized IIP membrane via simultaneous formation of IIP stucture and morphology (insitu) [5].…”

Section: Introductionmentioning

confidence: 99%

Selective transport of Fe(III) using ionic imprinted polymer (IIP) membrane particle

Djunaidi

Jumina

Siswanta

et al. 2015

AIP Conference Proceedings

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The membrane particles was prepared from polyvinyl alcohol (PVA) and polymer IIP with weight ratios of 1: 2 and 1: 1 using different adsorbent templates and casting thickness. The permeability of membrane towards Fe(III) and also mecanism of transport were studied. The selectivity of the membrane for Fe(III) was studied by performing adsorption experiments also with Cr(III) separately. In this study, the preparation of Ionic Imprinted Polymer (IIP) membrane particles for selective transport of Fe (III) had been done using polyeugenol as functional polymer. Polyeugenol was then imprinted with Fe (III) and then crosslinked with PEGDE under alkaline condition to produce polyeugenol-Fe-PEGDE polymer aggregates. The agrregates was then crushed and sieved using mesh size of 80 and the powder was then used to prepare the membrane particles by mixing it with PVA (Mr 125,000) solution in 1-Methyl-2-pyrrolidone (NMP) solvent. The membrane was obtained after casting at a speed of 25 m/s and soaking in NaOH solution overnight. The membrane sheet was then cut and Fe(III) was removed by acid to produce IIP membrane particles. Analysis of the membrane and its constituent was done by XRD, SEM and size selectivity test. Experimental results showed the transport of Fe(III) was faster with the decrease of membrane thickness, while the higher concentration of template ion correlates with higher Fe(III) being transported. However, the transport of Fe(III) was slower for higher concentration of PVA in the membrane. IImparticles works through retarded permeation mechanism, where Fe(III) was bind to the active side of IIP. The active side of IIP membrane was dominated by the-OH groups. The selectivity of all IIP membranes was confirmed as they were all unable to transport Cr (III), while NIP (Non-imprinted Polymer) membrane was able transport Cr (III).

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Section: Introductionmentioning

confidence: 99%

Selective transport of Fe(III) using ionic imprinted polymer (IIP) membrane particle

Djunaidi

Jumina

Siswanta

et al. 2015

AIP Conference Proceedings

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“…24 It is well-known as spice, precursor for synthetic vanillin production and is used in dental medicine since the 19 th century due to its antimicrobial activity. In polymer science, it found application as polyeugenol 25 or methacrylate 26 . Herein we present a novel sulfur copolymeric material from entirely sustainable resources prepared by inverse vulcanization of abundant, low cost by-product elemental sulfur and eugenol allyl ether obtained from renewable resources.…”

Section: Introductionmentioning

confidence: 99%

A sulfur–eugenol allyl ether copolymer: a material synthesized via inverse vulcanization from renewable resources and its application in Li–S batteries

Hoefling

Nguyen

Lee

et al. 2017

Mater. Chem. Front.

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The demand for environmentally friendly and sustainable resources have dramatically increased in scientific and technological areas including energy storage systems and production of new functional materials. Sulfur copolymers with high sulfur contents up to 90 wt% were prepared via inverse vulcanization from environment-friendly, sustainable raw materials: cost-effective waste-product elemental sulfur and eugenol allylether (EAE), which is obtained from clove oil. Thermal properties and electrochemical activities of the resulting poly(S-co-EAE) materials can be tuned by controlling EAE:S feed ratio. Employed as cathode materials in Li-S batteries, the copolymer with 90 wt% sulfur content provides a good cycling stability at the capacity ~650 mAhg -1 and high coulombic efficiencies (> 99 %) over 100 cycles.

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“…make eugenol has potential as a selective compound carrier. Eugenol has been widely used for the separation of heavy metals, including eugenol polymer (polyeugenol) used to adsorb ion Fe (III) [5,6], as a functional polymer in membrane in situ [7] and in particles membrane [8,9]. Polyeugenol that has many OH groups (bases hard) has been researced the possibility of using as the carrier for separating metal ions Cr 3+ [10] and the carrier compound that has active group N derived from polyeugenol has selective towards metal ion Cu 2+ with percent transport 87, 54% [11].…”

Section: Introductionmentioning

confidence: 99%

Separation of Cu²⁺, Cd²⁺and Cr³⁺in a Mixture Solution Using a Novel Carrier Poly(Methyl Thiazoleethyl Eugenoxy Acetate) with BLM (Bulk Liquid Membrane)

Djunaidi

Khabibi

Ulumudin

2017

IOP Conf. Ser.: Mater. Sci. Eng.

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Abstract. The separation process using a novel carrier polyeugenol has active groups N and S has been done with the technique BLM. Polyeugenol has groups active N and S was synthesized from eugenol which is then polymerized into polyeugenol. This polymeric compounds was then acidified become acidic poly (eugenoksi acetate). After the acid formed , then the synthesis was continued by add 4-methyl-5-tiazoleetanol to form esters poly (methyl thiazole eugenoxy ethyl acetate) (PMTEEA). IntroductionDue to the discharge of large amounts of metal-contaminated wastewater, industries bearing heavy metals, such as Cd, Cr, Cu, Ni, As, Pb, and Zn, are the most hazardous among the chemical-intensive industries. Because of their high solubility in the aquatic environments, heavy metals can be absorbed by living organisms. Once they enter the food chain, large concentrations of heavy metals may accumulate in the human body. If the metals are ingested beyond the permitted concentration, they can cause serious health disorders [1].One method for separating metal ions are liquid separation membrane [2]. In the liquid membrane technique, carrier compounds play an important function. Compounds carrier as a facilitator is determinant in the separation performance from the feed phase. A carrier compounds should has high ability to extraction via stable complex formation within the membrane, having high selective separation towards certain species, has good solubility as well as diffusion coefficient in the suitable organic solvent (membrane) and can be used in relatively a small amounts [3]. Besides that, a selectivity compounds carrier towards certain metal ions determined by the active groups on the carrier compound.Carrier compounds will form complexes with metal ions through chemical bonds between the active group with a metal ion, this establishment is based on the theory HSAB (Hard and Soft Acids Bases), this theory states that in general the metal acid hard ions (such as alkali, alkali earth, and Cr 3+ )

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Selective Transport of Fe(III) Using Polyeugenol as Functional Polymer with Ionic Imprinted Polymer Membrane Method

Cited by 13 publications

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Selective transport of Fe(III) using ionic imprinted polymer (IIP) membrane particle

Selective transport of Fe(III) using ionic imprinted polymer (IIP) membrane particle

A sulfur–eugenol allyl ether copolymer: a material synthesized via inverse vulcanization from renewable resources and its application in Li–S batteries

Separation of Cu²⁺, Cd²⁺and Cr³⁺in a Mixture Solution Using a Novel Carrier Poly(Methyl Thiazoleethyl Eugenoxy Acetate) with BLM (Bulk Liquid Membrane)

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Selective Transport of Fe(III) Using Polyeugenol as Functional Polymer with Ionic Imprinted Polymer Membrane Method

Cited by 13 publications

References 0 publications

Selective transport of Fe(III) using ionic imprinted polymer (IIP) membrane particle

Selective transport of Fe(III) using ionic imprinted polymer (IIP) membrane particle

A sulfur–eugenol allyl ether copolymer: a material synthesized via inverse vulcanization from renewable resources and its application in Li–S batteries

Separation of Cu2+, Cd2+and Cr3+in a Mixture Solution Using a Novel Carrier Poly(Methyl Thiazoleethyl Eugenoxy Acetate) with BLM (Bulk Liquid Membrane)

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Separation of Cu²⁺, Cd²⁺and Cr³⁺in a Mixture Solution Using a Novel Carrier Poly(Methyl Thiazoleethyl Eugenoxy Acetate) with BLM (Bulk Liquid Membrane)