Selective α-Carbon Hydroxylation of Glycine in Nickel(II)–Cyclotetrapeptide Complexes by Oxygen Metal complexes of biologically important ligands, Part 144. For Part 143 see: J. Schapp, W. Beck, Z. Naturforsch. 2002, 576, 280–284. This work was supported by the Deutsche Forschungsgemeinschaft and Fonds der Chemischen Industrie. We thank Professor Bernard Meunier, Tolouse, for a very valuable comment.

Coordinatively and Electronically Unsaturated Pentamethylcyclopentadienyliridium(III) Complexes with the Dianions of Biuret, of the Diamide of Malonic Acid and of anN-Acetyldipeptide Ester

“…These data can be obtained free of charge at www.ccdc.cam.ac.uk/conts/retrieving.html [or (1)ϪN (2) 80.0(2) Ir(1)ϪN (2) 198. 3(2) C(1)ϪN (1)ϪIr (1) 115.7(4) N(1)ϪC (1) 146. 8(9) N (1)ϪC (1)ϪC (2) 109.4(6) C(1)ϪC (2) 149.5(1) C(2)ϪN (2)ϪIr (1) 118.6(5) C(2)ϪN (2) 135.8 (8) Ir (1)ϪN (1) (1) 137.2 (9) Ir (1)ϪN (2)ϪC (6) 126.9(4) N(2)ϪC (6) 148.5(9) C(2)ϪN (2)ϪC (6) 114.2(6) C (7)ϪO (4) 121.7(9) C (7)ϪO (3) 134 . …”

Abnormal N‐heterocyclic Carbene Based Ni(II) π‐allyl Complex towards Molecular Oxygen Activation

“…In the last two decades, molecular oxygen activation by nickel complexes has drawn considerable attention from the perspective of catalysis and biochemistry [1–4] . Many nickel complexes display high reactivity towards O 2 and perform catalytic remote C−H oxidation using H 2 O 2 or O 2 as oxidant under mild conditions [5–10] .…”

Diastereomeric dinickel(ii) complexes with non-innocent bis(octaazamacrocyclic) ligands: isomerization, spectroelectrochemistry, DFT calculations and use in catalytic oxidation of cyclohexane

“…Transition metal complexes with redox non-innocent ligands are extensively studied in coordination chemistry to understand their electronic structure and bonding, 1–6 as well as to exploit their potential applicability in stoichiometric reactions 7,8 and catalytic transformations 9–11 inspired by metalloenzymes, e.g. , galactose oxidase.…”

“…Transition metal complexes with redox non-innocent ligands are extensively studied in coordination chemistry to understand their electronic structure and bonding, [1][2][3][4][5][6] as well as to exploit their potential applicability in stoichiometric reactions 7,8 and catalytic transformations [9][10][11] inspired by metalloenzymes, e.g., galactose oxidase. 12,13 While the number of mononuclear complexes with redox non-innocent ligands is large and permanently increases, the known examples of metal complexes with non-innocent dinucleating ligands are still scarce.…”