Selectivity controlled synthesis of furan-ring nitrogenous compounds from 5-hydroxymethylfurfural, ammonia and hydrogen peroxide

Gao, Xuan; Li, Zhihui; Zhang, Dongsheng; Zhao, Xinqiang; Wang, Yanji

doi:10.1039/d3cy01682j

Catal. Sci. Technol.

2024

DOI: 10.1039/d3cy01682j

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Selectivity controlled synthesis of furan-ring nitrogenous compounds from 5-hydroxymethylfurfural, ammonia and hydrogen peroxide

Xuan Gao,

Zhihui Li,

Dongsheng Zhang

et al.

Abstract: Nitrogenous compounds are significantly important for applications in chemicals and pharmaceuticals. A series of furan-ring nitrogenous compounds were synthesized using 5-hydroxymethylfurfural (HMF). The ammoximation of HMF with ammonia, hydrogen peroxide,...

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Cited by 7 publications

References 43 publications

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Bioactive Molecules from Lignocellulose‐Derived Platform Chemicals

Qiang,

Ansari,

Sun

et al. 2024

Adv Synth Catal

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The ever‐increasing prevalence of diseases and inadequate resources on Earth are threats to society. Biomass is an abundant resource, and bioactive compounds produced from biomass are environmentally benign in contrast to conventional chemical synthesis methods, which frequently depend on non‐renewable resources. In addition, the functionalized monomers from biomass allow the atom economical synthesis of bioactive molecules. This review aims to provide insight into the synthesis of bioactive molecules from the lignocellulose‐derived platform chemicals. Existing methodology and catalytic systems are summarized for the synthesis of targeted bioactive molecules from cellulose, hemicellulose, and lignin‐derived platform chemicals. The biological activities of bioactive molecules obtained from biomass, such as antioxidant, anti‐inflammatory, and anticancer properties, are discussed.

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Bioactive Molecules from Lignocellulose‐Derived Platform Chemicals

Qiang,

Ansari,

Sun

et al. 2024

Adv Synth Catal

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Recent Advances in the Synthesis and Application of TS‐1 Zeolite for Green Catalytic Oxidation

Wang,

Duan,

et al. 2024

Advanced Sustainable Systems

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TS‐1 has a unique structure, and TS‐1/H2O2 oxidation system for composition shows excellent catalytic performance in the oxidation of a variety of organic matter. The response conditions of the reaction system are mild, and the ultimate oxidation product is water. It is a typical “green catalytic” system and has received widespread attention from researchers. Here, the synthesis progress of TS‐1 to improve the accessibility and activity of active sites by doping mesoporous and microporous structures into traditional TS‐1 zeolite in recent five years are reviewed, including hydrothermal synthesis, dry gel conversion synthesis, solvent‐free synthesis, microwave assisted synthesis, and isomorphous substitution. Meanwhile, the application of TS‐1/H2O2 system in oxidative desulfurization, ketone ammonia oxidation, olefin epoxidation, and hydroxylation of aromatic hydrocarbons reactions are summarized and discussed. What's more, the reaction mechanism based on TS‐1/H2O2 system is proposed on regarding the isolated skeleton Ti site in titanium‐silicon zeolite as the active central site. Finally, the challenges and future development prospects of TS‐1 zeolite in synthesis and catalytic applications are predicted.

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Synthesis of bio-based caprolactam through dehydration and cyclization of 6-hydroxycaproamide

Zhai,

Ma,

Wang

2024

Res Chem Intermed

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Selectivity controlled synthesis of furan-ring nitrogenous compounds from 5-hydroxymethylfurfural, ammonia and hydrogen peroxide

Abstract: Nitrogenous compounds are significantly important for applications in chemicals and pharmaceuticals. A series of furan-ring nitrogenous compounds were synthesized using 5-hydroxymethylfurfural (HMF). The ammoximation of HMF with ammonia, hydrogen peroxide,...

Cited by 7 publications

References 43 publications

Bioactive Molecules from Lignocellulose‐Derived Platform Chemicals

Bioactive Molecules from Lignocellulose‐Derived Platform Chemicals

Recent Advances in the Synthesis and Application of TS‐1 Zeolite for Green Catalytic Oxidation

Synthesis of bio-based caprolactam through dehydration and cyclization of 6-hydroxycaproamide

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