Selectivity enhancement of Arsenazo(III) reagent towards heavier lanthanides using polyaminocarboxylic acids: A spectrophotometric study

Matharu, Komal; Mittal, Susheel K.; Kumar, Santosh; Sahoo, Suban K.

doi:10.1016/j.saa.2015.02.054

Cited by 17 publications

(4 citation statements)

References 48 publications

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“…Therefore, the concentration of cerium ions can be determined from the intensity of the absorption at 605 or 652 nm. 30 The intensity of the absorption peak at 652 nm was used as the standard for determining the cerium ion concentration. It is noteworthy that the color effect of Arsenazo III on hydrolyzed cerium ions is not obvious.…”

Section: Resultsmentioning

confidence: 99%

Highly efficient grafting of polyvinyl acetate onto cellulose nanocrystals in the aqueous phase

Liu

Zhou

et al. 2023

Green Chem.

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Section: Resultsmentioning

confidence: 99%

Highly efficient grafting of polyvinyl acetate onto cellulose nanocrystals in the aqueous phase

Liu

Zhou

et al. 2023

Green Chem.

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“…The method for determining the lutetium ions was based on the formation of a colored complex compound using the organic analytical reagent arsenazo III with the lutetium ions. To obtain an analytical form, it was necessary to introduce a colored reagent such as arsenazo III, which is a bisazo-derivative of chromotropic acid [ 34 , 63 ]. The calibration curve for determining the concentrations of lutetium (III) ions in the tested solutions is presented in Figure 2 .…”

Section: Methodsmentioning

confidence: 99%

Enhanced Lutetium Ion Sorption from Aqueous Solutions Using Activated Ion Exchangers

Jumadilov,

Khimersen,

Haponiuk

et al. 2024

Polymers

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The growing demand for rare earth elements (REE) requires the search for economically viable materials to efficiently recover REE from various solutions. Our research aims to investigate the potential of using a combination of the ion exchangers Lewatit CNP LF (in H+ form) and AV-17-8 (in OH− form) as an interpolymer system, “Lewatit CNP LF@AV-17-8” (X:Y), with varying mass ratios of X:Y to enhance the sorption efficiency of lutetium ions from nitrate solution. During the study, we used a range of analytical methodologies, including gravimetry, ultraviolet-visible (UV-VIS) spectroscopy, and inductively coupled plasma optical emission spectroscopy (ICP-OES). Our findings demonstrate that the interpolymer system “Lewatit CNP LF@AV-17-8” (X:Y), with a mass ratio of 4:2, exhibited a significantly enhanced sorption rate of Lu3+ ions (42%) compared to the individual Lewatit CNP LF (6:0) (25%) and the individual AV-17-8 (0:6) (21%) over a 48 h period. Moreover, this interpolymer system has demonstrated notable conformity to the Freundlich adsorption model, highlighting its performance as an effective sorbent for lutetium (III) ions. Notably, our study presents a novel utilization of the interpolymer system “Lewatit CNP LF@AV-17-8” (4:2), with an adsorption capacity of 221.05 mg/g, to enhance the recovery of lutetium ions. The research findings demonstrate its potential for enhancing the recovery of REE.

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“…The method for cerium ions determination was based on the formation of a colored complex compound of an organic analytical reagent arsenazo III with cerium ions. As known, cerium ions do not have a chromoform effect; therefore, to obtain an analytical form, it is necessary to use a colored reagent arsenazo III (bisazo-derivatives of chromotropic acid) [24].…”

Section: Plotting a Calibration Curvementioning

confidence: 99%

Ion Exchange Dynamics in Cerium Nitrate Solution Regulated by Remotely Activated Industrial Ion Exchangers

et al. 2021

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Many technological solutions contain valuable components as waste and can become an additional source of rare-earth elements to meet the needs of modern production. The development of technologies based on commercially available and cheap sorbents reveals the possibility for rare earth recovery from various solutions. This paper provides research on using a combination of KU-2-8 and AV-17-8 ion exchangers in different molar ratios for cerium ions sorption from its nitrate solution. The mutual activation of the ion exchangers in an aqueous medium provides their transformation into a highly ionized state by the conformational and electrochemical changes in properties during their remote interaction. The ion exchange dynamics of solutions were studied by the methods of electrical conductivity, pH measurements, and atomic emission analysis of the solutions. The research showed that the maximum activation of polymers was revealed within the molar ratio of KU-2-8:AV-17-8 equal to 3:3. In more detail, in comparison to AV-17-8, this interpolymer system showed an increase in the sorption degree by more than 1.5 times after 6 h of interaction. Moreover, compared with KU-2-8, the same interpolymer system showed an increase in the degree of cerium ions sorption by seven times after 24 h of interaction. As a result, the total cerium ions sorption degree after 48 h of sorption by individual KU-2-8 and AV-17-8 was 38% and 44%, respectively, whereas the cerium ions sorption degree by the same interpolymer system in the molar ratio 3:3 became 51%. An increase in the sorption degree of cerium ions by the interpolymer system in comparison with individual ion exchangers can be explained by the achievement of a high ionization degree of ion exchangers being activated in the interpolymer system by the remote interaction effect.

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Selectivity enhancement of Arsenazo(III) reagent towards heavier lanthanides using polyaminocarboxylic acids: A spectrophotometric study

Cited by 17 publications

References 48 publications

Highly efficient grafting of polyvinyl acetate onto cellulose nanocrystals in the aqueous phase

Highly efficient grafting of polyvinyl acetate onto cellulose nanocrystals in the aqueous phase

Enhanced Lutetium Ion Sorption from Aqueous Solutions Using Activated Ion Exchangers

Ion Exchange Dynamics in Cerium Nitrate Solution Regulated by Remotely Activated Industrial Ion Exchangers

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