1999
DOI: 10.1002/(sici)1521-3749(199910)625:10<1652::aid-zaac1652>3.0.co;2-q
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Selektive Darstellung zweifach diorganophosphido-verbrückter Metallatetrahedrane [Re2(MPR3)2(μ-PR2)2(CO)6] mit Re2M2-Metallgerüst (M = Au, Ag)

Abstract: A careful orchestration of protecting groups is an essential requirement for the total synthesis of the macrolide antibiotic bafilomycin A1 (1). Key steps were the Suzuki cross‐coupling reaction of two advanced, suitably protected intermediates prior to closure of the macrocycle, as well as a highly stereoselective methyl ketone aldol reaction.

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Cited by 7 publications
(4 citation statements)
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“…This, together with the inward bending of the Mo−M−Mo bonds in the ν 2 -squares, suggests the existence of attractive intramolecular d 10 −d 10 interactions between the group 11 metals. Examples of Cu−Ag, Cu−Au, , and Ag−Au ,,, , interactions have been reported in the literature.…”
Section: Resultsmentioning
confidence: 99%
“…This, together with the inward bending of the Mo−M−Mo bonds in the ν 2 -squares, suggests the existence of attractive intramolecular d 10 −d 10 interactions between the group 11 metals. Examples of Cu−Ag, Cu−Au, , and Ag−Au ,,, , interactions have been reported in the literature.…”
Section: Resultsmentioning
confidence: 99%
“…However the reaction principle was here successful only in the case of gold, not for the other coinage‐metals copper and silver [7] . Moreover, Haupt and co‐workers were successful inthe preparation of dirhenium metal clusters containing two bridging M(PR 3 ) fragments (M=Au, Ag) [8] . In this context, in 2012, the chemistry of gold under the special consideration of the isolobality concept as a guide in the synthesis of metal clusters was reviewed by Raubenheimer and Schmidbaur [9] .…”
Section: Introductionmentioning
confidence: 99%
“…[7] Moreover, Haupt and co-workers were successful inthe preparation of dirhenium metal clusters containing two bridging M(PR 3 ) fragments (M = Au, Ag). [8] In this context, in 2012, the chemistry of gold under the special consideration of the isolobality concept as a guide in the synthesis of metal clusters was reviewed by Raubenheimer and Schmidbaur. [9] Sometime later Adams and co-workers described the isolobal relationship between the molecules [Re 2 (CO) 8 (μ-H) 2 ] and the cluster [Re 2 {μ-Au(PPh 3 )} 2 (CO) 8 ].…”
Section: Introductionmentioning
confidence: 99%
“…Hence for the topomerization process the Re compounds always need a larger formal oxidation state than the corresponding Mn homologues and furthermore, partial contributions of metal and bridging orbitals in the formation of the HOMO is evident. (3) A change from Mn 2 Au 2 to M 1 M 2 Au 2 core (M 1 ≠ M 2 ) prevents the desired isomerization reaction9 .…”
mentioning
confidence: 99%