5Figure ES-2. Optimization of conditions for leaching Coal B with hydrochloric acid solutions (The selection of time/pH conditions in the dark green region should result in the removal of >30% of the sodium. Note also that a flag has been added to show the amount of sodium in the leach solution, 35% sodium removal, and the sodium content in the product ash).
Coal DCoal D showed significantly greater sodium removal than Coal B for similar treatment conditions. The treatability of Coal B is demonstrated in Figures ES3 to ES5. . Coal D leach results for hydrochloric acid solutions (Greater than 75% of the sodium was removed using pH 3 acidic solutions at a 1-hour treatment time. The initial sodium, reported as sodium oxide in the ash, was 6.16 %. The removal of over one-half of the sodium can be achieved using conditions of pH 5, 0.5 hours).
Recommended Future StudiesIt is recommended that future studies include, but not be limited to:• Investigation to determine if multiple leach solution contacts with new coal will allow recycle of the leach solution without detrimentally affecting the leachability of the coals and to produce a concentrated sodium bearing solution in order to limit the amount of leach solution that would have to be treated prior to water recycle or disposal.• Water cleanup will be required because of the relatively high sodium and chloride or sulfate content.• Evaluation of where and how the leachate could be introduced into the coal preparation treatment system. • Evaluation of the possible impact of pretreatment on the subsequent shipping and combustion processes.• The anticipated cost of the sodium cleansing treatment and subsequent water treatments.
INTRODUCTION
BackgroundThe US Department of Energy (DOE) Center for Advanced Separation Technologies (CAST), Great Northern Properties (GN), and the Montana Board Research and Commercialization Technology (MBRCT) are funding this project. The project is being administered and the research directed and conducted at CAMP. The intent of the project is to identify, and validate selected currently used (or previously studied) removal and sodium recovery treatment alternative(s) using laboratory bench-scale tests on four Montana coal samples. If the coals cannot be effectively treated by known techniques, alternative treatments will be developed. The evaluation of selected sodium removal technologies are presently underway and the following four stages are being and will be followed in future work: the successful removal of sodium from the coal so that the ash will content less than three percent, the rate at which the sodium ions are removed, characterization of the waste produced by sodium removal processing, and the overall economics of viable processes. Not part of the initial Project, but a necessary follow-up, will be the scale-up of the most appropriate sodium removal technology(s) in applications with companies using Clean Coal Technology to demonstrate sodium removal process or processes on a pilot scale.
Objective and ApproachThe overall ob...